Arene ruthenium(II) azido complexes incorporating N intersection O chelate ligands: Synthesis, spectral studies and 1,3-dipolar-cycloaddition to a coordinated azide in ruthenium(II) compounds
IR@NIO: CSIR-National Institute Of Oceanography, Goa
View Archive Info| Field | Value | |
| Creator |
Singh, K.S.
Kaminsky, W. |
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| Date |
2014-02-05T10:03:41Z
2014-02-05T10:03:41Z 2014 |
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| Identifier |
Polyhedron, vol.68; 2014; 279–286
http://drs.nio.org/drs/handle/2264/4462 |
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| Description |
The arene ruthenium(II) azido compounds [{(p-cymene)Ru(N^O)N<sub>3</sub>}] have been prepared by the reaction of [{(p-cymene)Ru(mewN<sub>3</sub>)Cl}<sub>2</sub>] with the corresponding ligands. The ruthenium azido compounds [{(p-cymene)Ru(N^O)N<sub>3</sub>}] undergo 1,3-dipolar additions with substituted alkynes at room temperature to give the (eta<sup>6</sup>-arene) ruthenium triazolato compounds [(p-cymene)Ru(N^O){N<sub>3</sub>C<sub>2</sub>(CO<sub>2</sub>R)<sub>2</sub>}]. The compounds were characterized on the basis of FTIR, NMR (<sup>1</sup>H and <sup>13</sup>C) and the molecular structure of a representative compound has been established with the help of single crystal X-ray diffraction.
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| Language |
en
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| Publisher |
Elsevier
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| Rights |
An edited version of this paper was published by Elsevier. Copyright [2013] Elsevier
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| Subject |
ligands
alkynes |
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| Title |
Arene ruthenium(II) azido complexes incorporating N intersection O chelate ligands: Synthesis, spectral studies and 1,3-dipolar-cycloaddition to a coordinated azide in ruthenium(II) compounds
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| Type |
Journal Article
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