Hydrometallurgical processing of spent lithium ion batteries (LIBs) in the presence of a reducing agent with emphasis on kinetics of leaching
IR@NML: CSIR-National Metallurgical Laboratory, Jamshedpur
View Archive Info| Field | Value | |
| Title |
Hydrometallurgical processing of spent lithium ion batteries (LIBs) in the presence of a reducing agent with emphasis on kinetics of leaching
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| Creator |
Meshram, Pratima
Pandey, B D Mankhand, T R |
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| Subject |
Waste Utilization
Hydrometallurgy Waste Management Waste Recycling |
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| Description |
In this study, sulfuric acid leaching was applied to recover lithium, cobalt, nickel and manganese from the
cathodic active material of spent LIBs in presence of a reducing agent, sodium bisulfite. The conditions for
the dissolution of valuable metals were optimized while varying the parameters such as acid concentration,leaching time, temperature and pulp density. It was found that with 1 M H2SO4 and 0.075 M NaHSO3 as reducing agent 96.7% Li, 91.6% Co, 96.4% Ni and 87.9% Mn were recovered in 4 h at 368 K and a pulp
density of 20 g/L. Kinetic data for the dissolution of the metals such as Li, Co and Ni in the temperature
range 308–368 K showed best fit to the kinetic model governed by the empirical logarithmic rate law.
Leaching of the metals proceeded through the diffusion of lixiviant on the surface of the substrate particles,
which was corroborated by XRD phase analyses and SEM–EDS of the untreated sample and the leach residues. From the leach liquor, >98% Co was recovered as cobalt oxalate (CoC2O42H2O) by precipitation with oxalic acid. MnCO3, NiCO3 and Li2CO3 were precipitated from the cobalt depleted solution. By this process, high recovery of Li and Co could be achieved in the solution and then in the form of carbonate and oxalate, respectively along with the recovery of Mn and Ni as their carbonates.
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| Publisher |
Elsevier
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| Date |
2015-06-23
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| Type |
Article
PeerReviewed |
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| Format |
application/pdf
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| Identifier |
http://eprints.nmlindia.org/7272/1/CEJ-LIBs.pdf
Meshram, Pratima and Pandey, B D and Mankhand, T R (2015) Hydrometallurgical processing of spent lithium ion batteries (LIBs) in the presence of a reducing agent with emphasis on kinetics of leaching. Chemical Engineering Journal, 281 (IF-5.310). pp. 418-427. |
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| Relation |
http://dx.doi.org/10.1016/j.cej.2015.06.071
http://eprints.nmlindia.org/7272/ |
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