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Influence of Mn incorporation for Ni on the magnetocaloric properties of rapidly solidified off-stoichiometric NiMnGa ribbons

IR@NML: CSIR-National Metallurgical Laboratory, Jamshedpur

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Title Influence of Mn incorporation for Ni on the magnetocaloric properties of rapidly solidified off-stoichiometric NiMnGa ribbons
 
Creator Dey, Sushmita
Singh, Satnam
Roy, Rajat K
Ghosh, M
Mitra, A
Panda, A K
 
Subject Applied Physics
 
Description The present investigation addresses the magnetocaloric behaviour in a series of Ni77-XMnXGa23 (x = 23, 24, 25, 27, 29) rapidly solidified alloys prepared in the form of ribbons by melt spinning technique. The approach of the study is to identify the off-stoichiometric composition wherein room temperature magneto-structural transformation is achieved. The alloy chemistry was tailored through Mn incorporation for Ni such that the magnetic and structural transitions were at close proximity to achieve highest entropy value of ΔS equal to 8.51 JKg-1K-1 for #Mn24 ribbon measured at an applied field of 3 Tesla. When such transitions are more staggered as in #Mn29 the entropy value of ribbon reduced to as low as 1.61 JKg-1K-1. Near room temperature transformations in #Mn24 ribbon have been observed through calorimetric and thermomagnetic evaluation. Reverse martensitic transformation (martensite autstenite) temperature indicates not only distinct change in the saturation flux density but also an inter-martensitic phase. Microstructural analysis of #Mn24alloy ribbon revealed structural ordering with the existence of plate morphology evidenced for martensitic phase
 
Publisher Elsevier
 
Date 2016
 
Type Article
NonPeerReviewed
 
Format application/pdf
 
Identifier http://eprints.nmlindia.org/7445/1/Magnetocaloric_NiMnGa.pdf
Dey, Sushmita and Singh, Satnam and Roy, Rajat K and Ghosh, M and Mitra, A and Panda, A K (2016) Influence of Mn incorporation for Ni on the magnetocaloric properties of rapidly solidified off-stoichiometric NiMnGa ribbons. Journal of Magnetism and Magnetic Materials, 397 (IF-2.630). pp. 342-346.
 
Relation http://dx.doi.org/10.1016/j.jmmm.2015.08.102
http://eprints.nmlindia.org/7445/