Cofacial Organic Click Cage to Intercalate Polycyclic Aromatic Hydrocarbons
IR@IICB: CSIR-Indian Institute of Chemical Biology, Kolkata
View Archive Info| Field | Value | |
| Title |
Cofacial Organic Click Cage to Intercalate Polycyclic Aromatic Hydrocarbons
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| Creator |
Samanta, Jayanta
Natarajan, Ramalingam |
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| Subject |
Chemistry
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| Description |
The synthesis of a 3-fold symmetric cofacial organic cage (COC) through Cu(I)-catalyzed azide−alkyne cycloaddition is reported. The COC can function as an efficient receptor for carcinogenic polycyclic aromatic hydrocarbons to intercalate them in its intrinsic cavity through donor−acceptor and π···π stacking interactions. The
association constants (Ka) are in the range of 3.7 × 104 to 1.3 × 106 M−1. X-ray diffraction analysis authenticated that the polycyclic aromatic hydrocarbons (PAHs) are
intercalated in the interior of the COC.
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| Publisher |
American Chemical Society
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| Date |
2016
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| Type |
Article
PeerReviewed |
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| Format |
application/pdf
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| Identifier |
http://www.eprints.iicb.res.in/2517/1/Organic_letters.pdf
Samanta, Jayanta and Natarajan, Ramalingam (2016) Cofacial Organic Click Cage to Intercalate Polycyclic Aromatic Hydrocarbons. Organic Letters. |
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| Relation |
http://dx.doi.org/10.1021/acs.orglett.6b01554
http://www.eprints.iicb.res.in/2517/ |
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