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Enhancement in magnetocaloric properties of NiMnGa alloy through stoichiometric tuned phase transformation and magneto-thermal transitions

IR@NML: CSIR-National Metallurgical Laboratory, Jamshedpur

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Title Enhancement in magnetocaloric properties of NiMnGa alloy through stoichiometric tuned phase transformation and magneto-thermal transitions
 
Creator Dey, Sushmita
Roy, Rajat K
Ghosh, M
Mallick, A Basu
Mitra, A
Panda, A K
 
Subject Applied Physics
Magnetic Properties
 
Description The investigation is focussed on phase generation and magnetocaloric properties of a series of Ni77-XMnXGa23 (x = 22, 23, 24, 25, 27) alloys prepared through arc melting furnace. With increase in Mn content, the alloys showed systematic transition from a non-modulated martensite (NM) to a fully austenitic parent phase through an appearance and coexistence of modulated (M) structure. Intermediate Mn containing alloy (#Mn-24) not only displayed high magnetic entropy change (Delta S-M) of -7.7 J/kg(-1)K(-1) but also large Refrigerant Capacity (RC) of 169 J.Kg(-1) at magnetic field change of 3 T compared to other alloys. The coexisting martensite (NM, M) and parent austenite as well as overlapping thermomagnetic and structural transformation was deliverable through tuning of alloy chemistry wherein Ni was systematically substituted by Mn. Transmission electron microscopy (TEM) supported the proposition with existence of martensite plates of different morphology in Mn-24 alloy exhibiting superior magnetocaloric properties. (C) 2017 Elsevier B.V. All rights reserved.
 
Publisher Elsevier
 
Date 2017-10-01
 
Type Article
PeerReviewed
 
Format application/pdf
 
Identifier http://eprints.nmlindia.org/7511/1/Dey_2017_305_311.pdf
Dey, Sushmita and Roy, Rajat K and Ghosh, M and Mallick, A Basu and Mitra, A and Panda, A K (2017) Enhancement in magnetocaloric properties of NiMnGa alloy through stoichiometric tuned phase transformation and magneto-thermal transitions. Journal of Magnetism and Magnetic Materials, 439 (IF-2.630). pp. 305-311.
 
Relation http://www.sciencedirect.com/science/article/pii/S0304885316329304
http://eprints.nmlindia.org/7511/