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Probing Highly Luminescent Europium-Doped Lanthanum Orthophosphate Nanorods for Strategic Applications

IR@NPL: CSIR-National Physical Laboratory, New Delhi

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Title Probing Highly Luminescent Europium-Doped Lanthanum Orthophosphate Nanorods for Strategic Applications
 
Creator Saraf, Mohit
Kumar, Pawan
Kedawat, Garima
Dwivedi, Jaya
Vithayathil, Sajna Antony
Jaiswal, Nagendra
Kaipparettu, Benny Abraham
Gupta, Bipin Kumar
 
Subject Inorganic Chemistry
Nuclear Chemistry
 
Description Herein we have established a strategy for the synthesis of highly luminescent and biocompatible europium-doped lanthanum orthophosphate (La0.85PO4Eu0.153+) nanorods. The structure and morphogenesis of these nanorods have been probed by XRD, SEM, and TEM/HRTEM techniques. The XRD result confirms that the as-synthesized nanorods form in a monazite phase with a monoclinic crystal structure. Furthermore, the surface morphology shows that the synthesized nanorods have an average diameter of similar to 90 nm and length of similar to 2 mu m. The HRTEM images show clear lattice fringes that support the presence of better crystal quality and enhanced photoluminescence hypersensitive red emission at 610 nm (D-5(0)-F-7(2)) upon 394 nm wavelength excitation. Furthermore, time-resolved spectroscopy and an MTT assay of these luminescent nanorods demonstrate a photoluminescent decay time of milliseconds with nontoxic behavior. Hence, these obtained results suggest that the as-synthesized luminescent nanorods could be potentially used in invisible security ink and high-contrast bioimaging applications.
 
Publisher American Chemical Society
 
Date 2015-03-16
 
Type Article
PeerReviewed
 
Format application/pdf
 
Identifier http://npl.csircentral.net/1954/1/261.pdf
Saraf, Mohit and Kumar, Pawan and Kedawat, Garima and Dwivedi, Jaya and Vithayathil, Sajna Antony and Jaiswal, Nagendra and Kaipparettu, Benny Abraham and Gupta, Bipin Kumar (2015) Probing Highly Luminescent Europium-Doped Lanthanum Orthophosphate Nanorods for Strategic Applications. Inorganic Chemistry, 54 (6). 2616-2625 . ISSN 0020-1669
 
Relation http://npl.csircentral.net/1954/