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Probing on phase dependent luminescent properties of Al2O3 nanowires for their performance in ferroelectric liquid crystal

IR@NPL: CSIR-National Physical Laboratory, New Delhi

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Title Probing on phase dependent luminescent properties of Al2O3 nanowires for their performance in ferroelectric liquid crystal
 
Creator Gangwar, Jitendra
Chandran, Achu
Joshi, Tilak
Verma, Rajni
Biradar, Ashok M
Tripathi, Surya Kant
Gupta, Bipin Kumar
Srivastava, Avanish Kumar
 
Subject Materials Science
 
Description Herein, we have investigated the various characteristics of two structurally different phases of Al2O3 nanowires: (i) gamma-Al2O3 (cubic) and (ii) gamma-Al2O3 (monoclinic). These nanowires were synthesized via hydrothermal treatment followed by calcination. The structural and luminescent properties were analyzed by scanning electron microscopy, high-resolution transmission electron microscopy and time-resolved photoluminescence spectroscopy. A plausible formation mechanism was proposed on the basis of experimental observations and analysis. These nanowires of both phases exhibit blue emission at similar to 466 nm (2.65 eV) upon 253 nm UV excitation wavelength. The time-resolved photoluminescence spectroscopy indicated that the decay time (tau) of theta-Al2O3 nanowires (tau = 273 picoseconds) is longer than that of gamma-Al2O3 nanowires (tau = 198 picoseconds). Moreover, these Al2O3 nanowires were dispersed in ferroelectric liquid crystal (FLC) to observe their effect on the electrooptical characteristics. The electro-optical response of the composite devices showed faster electrooptical response, thereby suggesting potential applications in electro-optical shutters and modulators.
 
Publisher IOP Publishing
 
Date 2015-07
 
Type Article
PeerReviewed
 
Format application/pdf
 
Identifier http://npl.csircentral.net/1956/1/263.pdf
Gangwar, Jitendra and Chandran, Achu and Joshi, Tilak and Verma, Rajni and Biradar, Ashok M and Tripathi, Surya Kant and Gupta, Bipin Kumar and Srivastava, Avanish Kumar (2015) Probing on phase dependent luminescent properties of Al2O3 nanowires for their performance in ferroelectric liquid crystal. Materials Research Express, 2 (7). 075013-1. ISSN 2053-1591
 
Relation http://npl.csircentral.net/1956/