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Nano-crystalline thin and nano-particulate thick TiO2 layer: Cost effective sequential deposition and study on dye sensitized solar cell characteristics

IR@CMERI: CSIR- Central Mechanical Engineering Research Institute (CMERI), Durgapur


Field	Value

Title	Nano-crystalline thin and nano-particulate thick TiO2 layer: Cost effective sequential deposition and study on dye sensitized solar cell characteristics

Creator	Das, P. Sengupta, D. Kasinadhuni, U. Mondal, B. Mukherjee, K.

Subject	Chemistry

Description	A compact thin TiO2 passivation layer is introduced between the mesoporous TiO2 nano-particulate layer and the conducting glass substrate to prepare photo-anode for dye-sensitized solar cell (DSSC). In order to understand the effect of passivation layer, other two DSSCs are also developed separately using TiO2 nano-particulate and compact thin film based photo-anodes. Nano-particles are prepared using hydrothermal synthesis route and the compact passivation layer is prepared by simply dip coating the precursor sol prepared through wet chemical route. The TiO2 compact layer and the nano-particles are characterised in terms of their micro-structural features and phase formation behavior. It is found that introduction of a compact TiO2 layer in between the mesoporous TiO2 nano-particulate layer and the conducting substrate improves the solar to electric conversion efficiency of the fabricated cell. The dense thin passivation layer is supposed to enhance the photo-excited electron transfer and prevent the recombination of photo-excited electrons.

Publisher	Elsevier

Date	2015

Type	Article PeerReviewed

Identifier	Das, P. and Sengupta, D. and Kasinadhuni, U. and Mondal, B. and Mukherjee, K. (2015) Nano-crystalline thin and nano-particulate thick TiO2 layer: Cost effective sequential deposition and study on dye sensitized solar cell characteristics. Materials Research Bulletin, 66. pp. 32-38.

Relation	http://cmeri.csircentral.net/247/