Mechanism of -O–O- bond activation and catalysis by RuIII-pac complexes (pac = polyaminocarboxylate)
IR@CMERI: CSIR- Central Mechanical Engineering Research Institute (CMERI), Durgapur
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Title |
Mechanism of -O–O- bond activation and catalysis by RuIII-pac complexes (pac = polyaminocarboxylate)
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Creator |
Chatterjee, Debabrata
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Subject |
Chemistry
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Description |
This paper presents the mechanistic aspects of the -O–O- bond activation by the Ru-pac (pac = polyaminocarboxylate) complex leading to the formation of various catalytic active species, viz. [RuIII(pac)(OOH)]2 − , [RuIV(pac)(OH)] − and [RuV(pac)(O)] − , and their reactivity towards oxidation of a few organic compounds.
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Publisher |
Springer Link
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Date |
2012-11
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Type |
Article
PeerReviewed |
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Identifier |
Chatterjee, Debabrata (2012) Mechanism of -O–O- bond activation and catalysis by RuIII-pac complexes (pac = polyaminocarboxylate). Journal of Chemical Sciences, 124 (6). pp. 1145-1150.
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Relation |
http://cmeri.csircentral.net/284/
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