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Mechanism of -O–O- bond activation and catalysis by RuIII-pac complexes (pac = polyaminocarboxylate)

IR@CMERI: CSIR- Central Mechanical Engineering Research Institute (CMERI), Durgapur

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Title Mechanism of -O–O- bond activation and catalysis by RuIII-pac complexes (pac = polyaminocarboxylate)
 
Creator Chatterjee, Debabrata
 
Subject Chemistry
 
Description This paper presents the mechanistic aspects of the -O–O- bond activation by the Ru-pac (pac = polyaminocarboxylate) complex leading to the formation of various catalytic active species, viz. [RuIII(pac)(OOH)]2 − , [RuIV(pac)(OH)] −  and [RuV(pac)(O)] − , and their reactivity towards oxidation of a few organic compounds.
 
Publisher Springer Link
 
Date 2012-11
 
Type Article
PeerReviewed
 
Identifier Chatterjee, Debabrata (2012) Mechanism of -O–O- bond activation and catalysis by RuIII-pac complexes (pac = polyaminocarboxylate). Journal of Chemical Sciences, 124 (6). pp. 1145-1150.
 
Relation http://cmeri.csircentral.net/284/