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Ceria nanoparticles vis-à-vis cerium nitrate as corrosion inhibitors for silica-alumina hybrid sol-gel coating

IR@NAL: CSIR-National Aerospace Laboratories, Bangalore

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Title Ceria nanoparticles vis-à-vis cerium nitrate as corrosion inhibitors for silica-alumina hybrid sol-gel coating
 
Creator Lakshmi, RV
Aruna, ST
Sampath, S
 
Subject Aeronautics (General)
Chemistry and Materials (General)
 
Description The present work provides a comparative study on the corrosion protection efficiency of defect free sol-gel hybrid coating containing ceria nanoparticles and cerium nitrate ions as corrosion inhibitors. Less explored organically modified alumina-silica hybrid sol-gel coatings are synthesized from 3-glycidoxypropyltrimethoxysilane and aluminium-tri-sec-butoxide. The microemulsion derived nanoparticles and the hybrid coatings are characterized and compared with coatings containing cerium nitrate. Corrosion inhibiting capability is assessed using electrochemical impedance spectroscopy. Scanning Kelvin probe measurements are also conducted on the coatings for identifying the apparent corrosion prone regions. Detailed X-ray photoelectron spectroscopy (XPS) analysis is carried out to comprehend the bonding and corrosion protection rendered by the hybrid coatings.
 
Publisher Elsevier science BV
 
Date 2016
 
Type Journal Article
PeerReviewed
 
Format application/pdf
 
Identifier http://nal-ir.nal.res.in/12527/1/RVL%2Dceria_particles%2DAPSUSC.pdf
Lakshmi, RV and Aruna, ST and Sampath, S (2016) Ceria nanoparticles vis-à-vis cerium nitrate as corrosion inhibitors for silica-alumina hybrid sol-gel coating. Applied Surface Science, 393 . pp. 397-404. ISSN 0169-4332
 
Relation http://dx.doi.org/10.1016/j.apsusc.2016.10.035
http://nal-ir.nal.res.in/12527/