Highly active InOx/TUD-1 catalyst towards Baeyer–Villiger oxidation of cyclohexanone using molecular oxygen and benzaldehyde
IR@CIMFR: CSIR-Central Institute of Mining and Fuel Research, Dhanbad
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| Title |
Highly active InOx/TUD-1 catalyst towards Baeyer–Villiger oxidation of cyclohexanone using molecular oxygen and benzaldehyde
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| Creator |
Pandey, J.K.
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| Subject |
Respiratory Protection Laboratory
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| Description |
InOx/TUD-1 is prepared by sol–gel method and characterized by different techniques. On the basis of different characterization results it is found that spongy porous InOx/TUD-1 (In/Si=8/100) matrix contains small crystallite of indium oxide in+3 oxidation state. InOx/TUD-1 (In/Si=8/100) catalyst shows good catalytic results for Baeyer–Villiger oxidation of cyclic ketones using molecular oxygen and sacrificial reagent benzaldehyde. The cyclohexanone conversion was found 100% with ε-caprolactone selectivity 100% using polar aprotic solvents e.g. dichloroethane, acetonitrile and benzonitrile in the presence of molecular oxygen.
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| Publisher |
Elsevier
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| Date |
2016-01
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| Type |
Article
PeerReviewed |
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| Format |
application/pdf
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| Identifier |
http://cimfr.csircentral.net/1672/1/26.%20Higly%20Active%20InOx%20TUD-1%20catalyst%20towards%20Baeyer-Villiger%20oxidation%20reaction.pdf
Pandey, J.K. (2016) Highly active InOx/TUD-1 catalyst towards Baeyer–Villiger oxidation of cyclohexanone using molecular oxygen and benzaldehyde. Catalysis Communications , 74. pp. 80-84. ISSN 1566-7367 |
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| Relation |
http://dx.doi.org/10.1016/j.catcom.2015.11.007
http://cimfr.csircentral.net/1672/ |
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