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Polyaniline/carbon nanotube/CdS quantum dot composites with enhanced optical and electrical properties

IR@CMERI: CSIR- Central Mechanical Engineering Research Institute (CMERI), Durgapur

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Title Polyaniline/carbon nanotube/CdS quantum dot composites with enhanced optical and electrical properties
 
Creator Goswami, Mrinmoy
Ghosh, Ranajit
Maruyama, Takahiro
Meikap, Ajit Kumar
 
Subject Materials
 
Description A new kind of polyaniline/carbon nanotube/CdS quantum dot composites have been developed via in-situ polymerization of aniline monomer in the presence of dispersed CdS quantum dots (size: 2.7–4.8 nm) and multi-walled carbon nanotubes (CNT), which exhibits enhanced optical and electrical properties. The existences of 1st order, 2nd order, and 3rd order longitudinal optical phonon modes, strongly indicate the high quality of synthesized CdS quantum dots. The occurrence of red shift of free exciton energy in photoluminescence is due to size dependent quantum confinement effect of CdS. The conductivity of the composites (for example PANI/CNT/CdS (2 wt.% CdS)) is increased by about 7 of magnitude compared to that of pure PANI indicating a charge transfer between CNT and polymer via CdS quantum dots. This advanced material has a great potential for high-performance of electro-optical applications.
 
Publisher Elsevier
 
Date 2016-02-28
 
Type Article
PeerReviewed
 
Identifier Goswami, Mrinmoy and Ghosh, Ranajit and Maruyama, Takahiro and Meikap, Ajit Kumar (2016) Polyaniline/carbon nanotube/CdS quantum dot composites with enhanced optical and electrical properties. Applied Surface Science, 364. pp. 176-180.
 
Relation http://cmeri.csircentral.net/406/