1,3-Dipolar cycloadditions. Part XXI: Catalytic effects of Lewis acids on 1,3-dipolar cycloaddition of <i style="">C</i>-(4-chlorophenyl)-<i style="">N</i>-phenyl nitrone to benzylidene acetophenone
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Title |
1,3-Dipolar cycloadditions. Part XXI: Catalytic effects of Lewis acids on 1,3-dipolar cycloaddition of <i style="">C</i>-(4-chlorophenyl)-<i style="">N</i>-phenyl nitrone to benzylidene acetophenone
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Creator |
Acharjee, Nivedita
Banerji, Avijit Prangé, Thierry |
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Subject |
1,3-Dipolar cycloadditions
Nitrone Benzylidene acetophenone Lewis acid catalyst |
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Description |
835-842
The normal electron demand reaction of <i style="">C</i>-chlorophenyl-<i style="">N</i>-phenyl nitrone with benzylidene acetophenone and the effects of mild Lewis acid catalysts like metal triflates and magnesium bromide on the reaction rate are reported. Frontier molecular orbital energies are calculated to rationalise the regioselectivity of the cycloaddition. |
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Date |
2011-06-07T09:44:25Z
2011-06-07T09:44:25Z 2011-06 |
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Type |
Article
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Identifier |
0975-0983(Online); 0376-4699(Print)
http://hdl.handle.net/123456789/11911 |
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Language |
en_US
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Rights |
<img src='http://nopr.niscair.res.in/image/cc-license-sml.png'> <a href='http://creativecommons.org/licenses/by-nc-nd/2.5/in' target='_blank'>CC Attribution-Noncommercial-No Derivative Works 2.5 India</a>
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Publisher |
NISCAIR-CSIR, India
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Source |
IJC-B Vol.50B(06) [June 2011]
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