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1,3-Dipolar cycloadditions. Part XXI: Catalytic effects of Lewis acids on 1,3-dipolar cycloaddition of <i style="">C</i>-(4-chlorophenyl)-<i style="">N</i>-phenyl nitrone to benzylidene acetophenone

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Title 1,3-Dipolar cycloadditions. Part XXI: Catalytic effects of Lewis acids on 1,3-dipolar cycloaddition of <i style="">C</i>-(4-chlorophenyl)-<i style="">N</i>-phenyl nitrone to benzylidene acetophenone
 
Creator Acharjee, Nivedita
Banerji, Avijit
Prangé, Thierry
 
Subject 1,3-Dipolar cycloadditions
Nitrone
Benzylidene acetophenone
Lewis acid catalyst
 
Description 835-842
The normal electron demand reaction of <i style="">C</i>-chlorophenyl-<i style="">N</i>-phenyl nitrone with benzylidene acetophenone and the effects of mild Lewis acid catalysts like metal triflates and magnesium bromide on the reaction rate are reported. Frontier molecular orbital energies are calculated to rationalise the regioselectivity of the cycloaddition.
 
Date 2011-06-07T09:44:25Z
2011-06-07T09:44:25Z
2011-06
 
Type Article
 
Identifier 0975-0983(Online); 0376-4699(Print)
http://hdl.handle.net/123456789/11911
 
Language en_US
 
Rights <img src='http://nopr.niscair.res.in/image/cc-license-sml.png'> <a href='http://creativecommons.org/licenses/by-nc-nd/2.5/in' target='_blank'>CC Attribution-Noncommercial-No Derivative Works 2.5 India</a>
 
Publisher NISCAIR-CSIR, India
 
Source IJC-B Vol.50B(06) [June 2011]