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Mild, efficient and economical oxidative deprotection of allyl aryl ethers

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Field Value
 
Title Mild, efficient and economical oxidative deprotection of allyl aryl ethers
 
Creator Lokhande, Pradeep D
Nawghare, Beena R
 
Subject Allyl aryl ethers
Dimethyl sulphoxide
Oxidative deprotection
 
Description 328-333
An efficient, economical procedure for the cleavage of allyl aryl ethers using a catalytic amount of iodine in dimethyl sulphoxide gives corresponding alcohols or phenols in high yields under mild condition. The reaction can be performed in air without loss of variety of oxidisable fuctional groups. Allyl ether of phenols is selectively deprotected in preference to alcohols. The reaction is highly regioselective and chemoselective.
 
Date 2012-01-14T19:06:00Z
2012-01-14T19:06:00Z
2012-01
 
Type Article
 
Identifier 0975-0983(Online); 0376-4699(Print)
http://hdl.handle.net/123456789/13402
 
Language en_US
 
Rights <img src='http://nopr.niscair.res.in/image/cc-license-sml.png'> <a href='http://creativecommons.org/licenses/by-nc-nd/2.5/in' target='_blank'>CC Attribution-Noncommercial-No Derivative Works 2.5 India</a>
 
Publisher NISCAIR-CSIR, India
 
Source IJC-B Vol.51B(01) [January 2012]