Kinetics of oxidation of bisulphite ion by iron (III) in the presence of 1,10-phenanthroline
IR@NISCAIR: CSIR-NISCAIR, New Delhi - ONLINE PERIODICALS REPOSITORY (NOPR)
View Archive Info| Field | Value | |
| Title |
Kinetics of oxidation of bisulphite ion by iron (III) in the presence of 1,10-phenanthroline
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| Creator |
Mohapatra, S K
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| Description |
709-710
The title reaction has been investigated under pseudo-unimolecular conditions with [phen] > [HSO<img src='/image/spc_char/3_bar.gif' border=0>] > [Fe(III)]. The reaction obeys first order kinetics in [Fe(III)]. The kinetics is interpreted in terms of an inner-sphere reduction of Fe(phen)<img src='http://www.niscair.res.in/jinfo/equation28.gif' border=0> via formation of the reactive intermediate Fe(phen)<sub>2</sub>-(SO<sub>3</sub>H)<sup>2+</sup>. |
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| Date |
2018-03-20T10:47:42Z
2018-03-20T10:47:42Z 1993-08 |
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| Type |
Article
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| Identifier |
0975-0975(Online); 0376-4710(Print)
http://nopr.niscair.res.in/handle/123456789/43945 |
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| Language |
en_US
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| Rights |
<img src='http://nopr.niscair.res.in/image/cc-license-sml.png'> <a href='http://creativecommons.org/licenses/by-nc-nd/2.5/in' target='_blank'>CC Attribution-Noncommercial-No Derivative Works 2.5 India</a>
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| Publisher |
NISCAIR-CSIR, India
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| Source |
IJC-A Vol.32A(08) [August 1993]
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