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Synthesis and characterization of some polyalkyl- and polyalkoxy-anilines

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Title Synthesis and characterization of some polyalkyl- and polyalkoxy-anilines
 
Creator Ahmad, Naseer
Feng, Ping
Schursky, Helen
Shah, Sharmila
Antonacci, Desiree
Cichowicz, Melissa B
Kohli, Rakesh K
MacDiarmid, Alan G
 
Description 673-678
Since poly-3-alkylthiophenes are more processible than polythiophene, it is expected that poly-<em>o</em>-alkyl and poly-<em>o</em>-alkoxyanilines will evince better processibility than polyaniline. Hence, poly-<em>o</em>-alkyl and poly-<em>o</em>-alkoxyanilines (alkyl = CH<sub>3</sub>, C<sub>2</sub>H<sub>5</sub>, C<sub>3</sub>H<sub>7</sub>, alkoxy = OCH<sub>3</sub>, OC<sub>2</sub>H<sub>5</sub>, OC<sub>3</sub>H<sub>7</sub>) have been synthesized. The polyaniline salt is insoluble in organic solvents but these polymers are soluble both in salt and base forms. The solubility increases with increase in the length of the side chain but conductivity decreases. The polypropyl and polypropoxyanilines have been synthesized for the first time.
 
Date 2018-03-20T11:50:52Z
2018-03-20T11:50:52Z
1993-08
 
Type Article
 
Identifier 0975-0975(Online); 0376-4710(Print)
http://nopr.niscair.res.in/handle/123456789/43953
 
Language en_US
 
Rights <img src='http://nopr.niscair.res.in/image/cc-license-sml.png'> <a href='http://creativecommons.org/licenses/by-nc-nd/2.5/in' target='_blank'>CC Attribution-Noncommercial-No Derivative Works 2.5 India</a>
 
Publisher NISCAIR-CSIR, India
 
Source IJC-A Vol.32A(08) [August 1993]