Mass spectral studies on quadruply bonded molybdenum complexes, Mo<sub>2</sub>(S<sub>2</sub>PF<sub>2</sub>)<sub>4</sub> and Mo<sub>2</sub>(S<sub>2</sub>PMe<sub>2</sub>)<sub>4</sub>
IR@NISCAIR: CSIR-NISCAIR, New Delhi - ONLINE PERIODICALS REPOSITORY (NOPR)
View Archive Info| Field | Value | |
| Title |
Mass spectral studies on quadruply bonded molybdenum complexes, Mo<sub>2</sub>(S<sub>2</sub>PF<sub>2</sub>)<sub>4</sub> and Mo<sub>2</sub>(S<sub>2</sub>PMe<sub>2</sub>)<sub>4</sub>
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| Creator |
Islam, M Quamrul
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| Description |
797-798
The electron impact mass spectrum of Mo<sub>2</sub>(S<sub>2</sub>PF<sub>2</sub>)<sub>4</sub> shows the molecular ion which releases a PF<sub>2</sub> group to produce the most abundant ion, Mo<sub>2</sub>S<sub>8</sub>P<sub>3</sub>F. This ion fragments by releasing a series of groups such as PF<sub>2</sub>, PFS and PF<sub>2</sub>S, For Mo<sub>2</sub>(S<sub>2</sub>PMe<sub>2</sub>)<sub>4 </sub> Desorption Chemical Ionization (DCI) technique is required to see the molecular ion. The parent ion fragments by the loss of Me<sub>2</sub>S, PMe<sub>2</sub>S and PMe<sub>3</sub> groups. Loss of PMe<sub>3</sub> from molecular ion suggests rearrangement before fragmentation-a process not observed for Mo<sub>2</sub>(S<sub>2</sub>PF<sub>2</sub>)<sub>4</sub>. The difference in mass spectral fragmentation patterns is in agreement with the different structures of the two compounds. |
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| Date |
2018-03-21T08:30:39Z
2018-03-21T08:30:39Z 1993-09 |
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| Type |
Article
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| Identifier |
0975-0975(Online); 0376-4710(Print)
http://nopr.niscair.res.in/handle/123456789/43968 |
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| Language |
en_US
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| Rights |
<img src='http://nopr.niscair.res.in/image/cc-license-sml.png'> <a href='http://creativecommons.org/licenses/by-nc-nd/2.5/in' target='_blank'>CC Attribution-Noncommercial-No Derivative Works 2.5 India</a>
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| Publisher |
NISCAIR-CSIR, India
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| Source |
IJC-A Vol.32A(09) [September 1993]
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