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Spectrophotometric study of acid-base equilibria of 4-(2-benzothiazolylazo)resorcinol and 4-(2-benzothiazolylazo)salicylic acid

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Title Spectrophotometric study of acid-base equilibria of 4-(2-benzothiazolylazo)resorcinol and 4-(2-benzothiazolylazo)salicylic acid
 
Creator Abu-Bakr, Mohamed S
El-Shahawy, Anwar S
Ahmed, Seddique M
 
Description 789-793
The visible absorption spectra of 4-(2-benzothiazolylazo)resorcinol and 4-(2-benzothiazolylazo) salicyclic acid have been recorded in aquo-organic solvent mixtures in the <em>p</em>H range 0.5-12.0. The spectral changes have been explained in terms of shifts in equilibria amongst different molecular and ionic species of BTAR and BTAS existing in solution. The <em>pK</em><sub>a</sub> values corresponding to the different ionisation steps have been determined at 25°C and 1=0.1 <em>M </em> (KNO<sub>3</sub>) by graphical analysis of the absorbance-<em>p</em>H curves.
 
Date 2018-03-21T08:44:32Z
2018-03-21T08:44:32Z
1993-09
 
Type Article
 
Identifier 0975-0975(Online); 0376-4710(Print)
http://nopr.niscair.res.in/handle/123456789/43970
 
Language en_US
 
Rights <img src='http://nopr.niscair.res.in/image/cc-license-sml.png'> <a href='http://creativecommons.org/licenses/by-nc-nd/2.5/in' target='_blank'>CC Attribution-Noncommercial-No Derivative Works 2.5 India</a>
 
Publisher NISCAIR-CSIR, India
 
Source IJC-A Vol.32A(09) [September 1993]