Homolytic displacement at saturated carbon in organocobaloximes: Part VI† - Synthesis of benzyl sulphones
IR@NISCAIR: CSIR-NISCAIR, New Delhi - ONLINE PERIODICALS REPOSITORY (NOPR)
View Archive Info| Field | Value | |
| Title |
Homolytic displacement at saturated carbon in organocobaloximes: Part VI† - Synthesis of benzyl sulphones
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| Creator |
Gupta, B D
Das, Indira Dixit, Yandana |
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| Description |
762-766
The reactions of thiophene-2-sulphonyl chloride with benzyl and <em>para</em>-substituted benzyl cobaloximes under anaerobic and photochemical conditions at 0°C give benzyl sulphones and bibenzyls in variable yields. However, the reactions with heteroaromatic methyl cobaloximes give the corresponding sulphones as the exclusive organic products. The reactions are interpreted in terms of S<sub>H</sub>2 mechanism. |
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| Date |
2018-03-21T09:53:47Z
2018-03-21T09:53:47Z 1993-09 |
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| Type |
Article
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| Identifier |
0975-0975(Online); 0376-4710(Print)
http://nopr.niscair.res.in/handle/123456789/43976 |
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| Language |
en_US
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| Rights |
<img src='http://nopr.niscair.res.in/image/cc-license-sml.png'> <a href='http://creativecommons.org/licenses/by-nc-nd/2.5/in' target='_blank'>CC Attribution-Noncommercial-No Derivative Works 2.5 India</a>
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| Publisher |
NISCAIR-CSIR, India
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| Source |
IJC-A Vol.32A(09) [September 1993]
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