Effect of solvents on the reaction between phenacyl bromide and triethylamine
IR@NISCAIR: CSIR-NISCAIR, New Delhi - ONLINE PERIODICALS REPOSITORY (NOPR)
View Archive Info| Field | Value | |
| Title |
Effect of solvents on the reaction between phenacyl bromide and triethylamine
|
|
| Creator |
Pillay, M Krishna
Nallu, M |
|
| Description |
897-898
Rate constants for the reaction of ɑ-halogenocarbonyl compound such as phenacyl bromide with triethylamine in various solvents at 25ᵒ, 30ᵒ and 35ᵒC have been determined. A plot of log <em>k</em><sub>2</sub> of BrCH<sub>2</sub>COPh + NEt reaction versus log <em>k</em><sub>2</sub> of BrCH<sub>2</sub>COOEt + NEt reaction is linear in some solvents. Simple and multiple correlations of log <em>k</em><sub>2</sub> at 30ᵒ for the reaction between PhCOCH<sub>2</sub>Br and Net<sub>3</sub>) with several solvent parameters at macroscopic and microscopic levels are found to be successful. |
|
| Date |
2018-03-26T04:53:32Z
2018-03-26T04:53:32Z 1993-10 |
|
| Type |
Article
|
|
| Identifier |
0975-0975(Online); 0376-4710(Print)
http://nopr.niscair.res.in/handle/123456789/44029 |
|
| Language |
en_US
|
|
| Rights |
<img src='http://nopr.niscair.res.in/image/cc-license-sml.png'> <a href='http://creativecommons.org/licenses/by-nc-nd/2.5/in' target='_blank'>CC Attribution-Noncommercial-No Derivative Works 2.5 India</a>
|
|
| Publisher |
NISCAIR-CSIR, India
|
|
| Source |
IJC-A Vol.32A(10) [October 1993]
|
|