Kinetics of oxidation of substituted 2-phenylthiazolidines by pyridinium chlorochromate
IR@NISCAIR: CSIR-NISCAIR, New Delhi - ONLINE PERIODICALS REPOSITORY (NOPR)
View Archive Info| Field | Value | |
| Title |
Kinetics of oxidation of substituted 2-phenylthiazolidines by pyridinium chlorochromate
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| Creator |
Ananthakrishnanadar, P
Prabhakaran, T R |
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| Description |
877-880
Kinetics of oxidation of 2-phenylthiazolidine (PT) and substituted PI (SPT) by pyridinium chlorochromate (PCC) in dry acetic acid have been investigated. The reaction is first order in FCC and fractional order in PT and it exhibits Michaelis-Menten kinetic character. The complex formation constants (<em>K</em>) and the decomposition rate constants (<em>k</em><sub>1</sub>) have been computed from the double reciprocal plots of 1/<em>k</em><sub>obs</sub> versus 1/[PT]<sub>0</sub>. The decomposition rate constants are not correlated by Hammett σ constants. Nevertheless, they show satisfactory correlation with σ<sub>1</sub> and σ<sub>2</sub> parameters. The correlation with Swain and Lupton F and R values is relatively less satisfactory. |
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| Date |
2018-03-26T05:04:04Z
2018-03-26T05:04:04Z 1993-10 |
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| Type |
Article
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| Identifier |
0975-0975(Online); 0376-4710(Print)
http://nopr.niscair.res.in/handle/123456789/44035 |
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| Language |
en_US
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| Rights |
<img src='http://nopr.niscair.res.in/image/cc-license-sml.png'> <a href='http://creativecommons.org/licenses/by-nc-nd/2.5/in' target='_blank'>CC Attribution-Noncommercial-No Derivative Works 2.5 India</a>
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| Publisher |
NISCAIR-CSIR, India
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| Source |
IJC-A Vol.32A(10) [October 1993]
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