Kinetics of oxidative hydrolysis of aromatic anils by potassium Bromated
IR@NISCAIR: CSIR-NISCAIR, New Delhi - ONLINE PERIODICALS REPOSITORY (NOPR)
View Archive Info| Field | Value | |
| Title |
Kinetics of oxidative hydrolysis of aromatic anils by potassium Bromated
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| Creator |
Ramakrishnan, Kalyani
Srinivasan, Vangalur S |
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| Description |
873-876
The kinetics of oxidative hydrolysis of aromatic anils by potassium bromate have been studied in acetic acid (50%, v/v) containing HCIO<sub>4</sub> (0.20 mol dm<sup>-3</sup>) at 27±0.2ᵒC in the presence of Hg(OAc)<sub>2</sub> (0.01 mol dm<sup>-3</sup>). The reaction exhibits total second order kinetics-first order in each reactant. The presence of electron withdrawing group like <em>p-</em>NO<sub>2</sub> in the aniline portion increases the rate markedly. A mechanism involving nitrene intermediate, is proposed to account for the stoichiometry and products, namely, benzaldehyde and azobenzene. |
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| Date |
2018-03-26T05:06:34Z
2018-03-26T05:06:34Z 1993-10 |
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| Type |
Article
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| Identifier |
0975-0975(Online); 0376-4710(Print)
http://nopr.niscair.res.in/handle/123456789/44036 |
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| Language |
en_US
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| Rights |
<img src='http://nopr.niscair.res.in/image/cc-license-sml.png'> <a href='http://creativecommons.org/licenses/by-nc-nd/2.5/in' target='_blank'>CC Attribution-Noncommercial-No Derivative Works 2.5 India</a>
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| Publisher |
NISCAIR-CSIR, India
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| Source |
IJC-A Vol.32A(10) [October 1993]
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