Oxidation chemistry of 2,8-dihydroxyadenine at a pyrolytic graphite electrode
IR@NISCAIR: CSIR-NISCAIR, New Delhi - ONLINE PERIODICALS REPOSITORY (NOPR)
View Archive Info| Field | Value | |
| Title |
Oxidation chemistry of 2,8-dihydroxyadenine at a pyrolytic graphite electrode
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| Creator |
Goyal, R N
Mittal, Alok |
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| Description |
852-856
The electrochemical oxidation of 2,8-dihydroxyadenine has been studied at a pyrolytic graphite electrode in the <em>p</em>H range 3.0-11.2. The oxidation of 2,8-dihydroxyadenine proceeds in a single 2e, 2H<sup>+</sup> step to give the corresponding diimine, which on follow up chemical reactions gives allantoin at <em>p</em>H 7.5 and parabanic acid, alloxan and urea at <em>p</em>H 3.0. An EC mechanism for the electrochemical oxidation of 2,8-dihydroxyadenine has also been suggested. |
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| Date |
2018-03-26T05:14:39Z
2018-03-26T05:14:39Z 1993-10 |
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| Type |
Article
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| Identifier |
0975-0975(Online); 0376-4710(Print)
http://nopr.niscair.res.in/handle/123456789/44040 |
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| Language |
en_US
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| Rights |
<img src='http://nopr.niscair.res.in/image/cc-license-sml.png'> <a href='http://creativecommons.org/licenses/by-nc-nd/2.5/in' target='_blank'>CC Attribution-Noncommercial-No Derivative Works 2.5 India</a>
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| Publisher |
NISCAIR-CSIR, India
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| Source |
IJC-A Vol.32A(10) [October 1993]
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