Naphthalene quenching of benzophenone sensitized reactions of pentacyanonitrosylferrate (II), [Fe(CN)<sub>5</sub>NO]<sup>2-</sup>
IR@NISCAIR: CSIR-NISCAIR, New Delhi - ONLINE PERIODICALS REPOSITORY (NOPR)
View Archive Info| Field | Value | |
| Title |
Naphthalene quenching of benzophenone sensitized reactions of pentacyanonitrosylferrate (II), [Fe(CN)<sub>5</sub>NO]<sup>2-</sup>
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| Creator |
Sidhu, S
Bansal, W R (Ms) Sumanjit |
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| Description |
847-851
The title investigation is reported under conditions either favourable to energy transfer from <sup>3</sup>BP (benzophenone) to pentacyanonitrosylferrate(II), (NP), which gives [Fe(CN)<sub>5</sub>CH<sub>3</sub>OH]<sup>2-</sup>, (LSP), or hydrogen abstraction by <sup>3</sup>BP from propane-2-ol which gives [Fe(CN)<sub>4</sub>NO]<sup>2-</sup>, (TNF). In the former system naphthalene (NA) quenches the reaction upto its concentration < 1.0 x 10<sup>-2</sup> mol dm<sup>-3</sup> beyond which φ<sub>LSP</sub> (0.12) is constant. In the latter system NA completely quenches the formation of TNF with a concomitant increase in φ<sub>LSP</sub>. The experimental data which is consistent with the proposed mechanism supports the quenching of <sup>3</sup>BP and subsequent energy transfer from the resulting <sup>3</sup>NA to NP. |
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| Date |
2018-03-26T05:16:58Z
2018-03-26T05:16:58Z 1993-10 |
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| Type |
Article
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| Identifier |
0975-0975(Online); 0376-4710(Print)
http://nopr.niscair.res.in/handle/123456789/44041 |
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| Language |
en_US
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| Rights |
<img src='http://nopr.niscair.res.in/image/cc-license-sml.png'> <a href='http://creativecommons.org/licenses/by-nc-nd/2.5/in' target='_blank'>CC Attribution-Noncommercial-No Derivative Works 2.5 India</a>
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| Publisher |
NISCAIR-CSIR, India
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| Source |
IJC-A Vol.32A(10) [October 1993]
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