Solvation behaviour of copper(II) chloride in some isodielectric media
IR@NISCAIR: CSIR-NISCAIR, New Delhi - ONLINE PERIODICALS REPOSITORY (NOPR)
View Archive Info| Field | Value | |
| Title |
Solvation behaviour of copper(II) chloride in some isodielectric media
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| Creator |
Singh, Prem P
Soni, Manjula |
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| Description |
837-841
Solvation behaviour of copper(II) chloride has been investigated in formamide (FD) or N-methylformamide (NMFD) + 1,4-dioxane (D) or N,N-dimethylformamide (DMF) media, isodielectric with water (W) by emf measurements at 303.15 K on the Cu/Hg<sub>x</sub>/CuCl<sub>2</sub> (FD or NMFD + D or DMF)/AgCl/Ag cell. The cell emf which varies as NMFD + D) < E(FD + D) < E(FD + DMF) has been shown, by graph-theoretical rationalization, to be dictated by the molecular species present in them. The dissociation constant, degree of dissociation of CuCl<sub>2</sub> and the standard cell potentials have also been determined, by iterative procedures, in these media. The molar Gibbs free energy of transfer of CuCl<sub>2</sub> from W→ (FD or NMFD + D or DMF) has also been determined and its analysis suggests that it arises, in the present case, due to changes in the interactions of the ions of CuCl<sub>2</sub> in these media. |
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| Date |
2018-03-26T05:20:16Z
2018-03-26T05:20:16Z 1993-10 |
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| Type |
Article
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| Identifier |
0975-0975(Online); 0376-4710(Print)
http://nopr.niscair.res.in/handle/123456789/44043 |
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| Language |
en_US
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| Rights |
<img src='http://nopr.niscair.res.in/image/cc-license-sml.png'> <a href='http://creativecommons.org/licenses/by-nc-nd/2.5/in' target='_blank'>CC Attribution-Noncommercial-No Derivative Works 2.5 India</a>
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| Publisher |
NISCAIR-CSIR, India
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| Source |
IJC-A Vol.32A(10) [October 1993]
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