CSIR Central

Determination of sugar acids and related compounds by vanadium(V) in perchloric acid: The product analysis and probable mechanism of oxidation

IR@NISCAIR: CSIR-NISCAIR, New Delhi - ONLINE PERIODICALS REPOSITORY (NOPR)

View Archive Info
 
 
Field Value
 
Title Determination of sugar acids and related compounds by vanadium(V) in perchloric acid: The product analysis and probable mechanism of oxidation
 
Creator Banerjee, Amalendu
Putatunda, Anuva
Mandai, Dinabandhu
Hazra, Banasri
Banerjee, Gopal Chandra
Dutt, Sachchidananda
 
Description 1099-1101
A mixture of the reductant and an excess of Na(or NH<sub>4</sub>)VO<sub>3</sub>, in dilute HClO<sub>4</sub> has been slowly refluxed for 40 min and the residual metavanadate determined iodometrically. The metavanadate has been standardized against either Na<sub>2</sub>S<sub>2</sub>O<sub>3</sub> or the respective reductant of known strength for better results. The product analysis, the probable reaction mechanism, the methods for removal of interferants and the detection of adulterants in aldoses have been reported.
 
Date 2018-03-26T08:19:59Z
2018-03-26T08:19:59Z
1993-12
 
Type Article
 
Identifier 0975-0975(Online); 0376-4710(Print)
http://nopr.niscair.res.in/handle/123456789/44072
 
Language en_US
 
Rights <img src='http://nopr.niscair.res.in/image/cc-license-sml.png'> <a href='http://creativecommons.org/licenses/by-nc-nd/2.5/in' target='_blank'>CC Attribution-Noncommercial-No Derivative Works 2.5 India</a>
 
Publisher NISCAIR-CSIR, India
 
Source IJC-A Vol.32A(12) [December 1993]