Kinetics and mechanism of oxidation of nitrilotriacetate by poly(pyrldyl)iron(III) complexes and dodecatungstocobaltate(III) ion - A comparative study
IR@NISCAIR: CSIR-NISCAIR, New Delhi - ONLINE PERIODICALS REPOSITORY (NOPR)
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Title |
Kinetics and mechanism of oxidation of nitrilotriacetate by poly(pyrldyl)iron(III) complexes and dodecatungstocobaltate(III) ion - A comparative study
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Creator |
Ayoko, G Adefikayo
Guinea, Papua New lyun, J Femii Mamman, Saratu |
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Description |
1089-1091
Kinetics of oxidation of nitrilotriacetate by Fe(LL)<img src='http://www.niscair.res.in/jinfo/equation149.gif' border=0> (<img src='http://www.niscair.res.in/jinfo/small.gif' border=0>-phenanthroline or bipyridine) and CoW<sub>12</sub>O<img src='http://www.niscair.res.in/jinfo/equation150.gif' border=0> have been investigated in aqueous acidic media. The reaction is first order each in reductant and oxidants but inversely proportional to acid concentration. The reactions are analysed by means of Schuster treatment of outer-sphere electron-transfer. |
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Date |
2018-03-26T08:28:37Z
2018-03-26T08:28:37Z 1993-12 |
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Type |
Article
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Identifier |
0975-0975(Online); 0376-4710(Print)
http://nopr.niscair.res.in/handle/123456789/44075 |
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Language |
en_US
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Rights |
<img src='http://nopr.niscair.res.in/image/cc-license-sml.png'> <a href='http://creativecommons.org/licenses/by-nc-nd/2.5/in' target='_blank'>CC Attribution-Noncommercial-No Derivative Works 2.5 India</a>
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Publisher |
NISCAIR-CSIR, India
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Source |
IJC-A Vol.32A(12) [December 1993]
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