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Kinetics and mechanism of oxidation of nitrilotriacetate by poly(pyrldyl)iron(III) complexes and dodecatungstocobaltate(III) ion - A comparative study

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Title Kinetics and mechanism of oxidation of nitrilotriacetate by poly(pyrldyl)iron(III) complexes and dodecatungstocobaltate(III) ion - A comparative study
 
Creator Ayoko, G Adefikayo
Guinea, Papua New
lyun, J Femii
Mamman, Saratu
 
Description 1089-1091
Kinetics of oxidation of nitrilotriacetate by Fe(LL)<img src='http://www.niscair.res.in/jinfo/equation149.gif' border=0> (<img src='http://www.niscair.res.in/jinfo/small.gif' border=0>-phenanthroline or bipyridine) and CoW<sub>12</sub>O<img src='http://www.niscair.res.in/jinfo/equation150.gif' border=0> have been investigated in aqueous acidic media. The reaction is first order each in reductant and oxidants but inversely proportional to acid concentration. The reactions are analysed by means of Schuster treatment of outer-sphere electron-transfer.
 
Date 2018-03-26T08:28:37Z
2018-03-26T08:28:37Z
1993-12
 
Type Article
 
Identifier 0975-0975(Online); 0376-4710(Print)
http://nopr.niscair.res.in/handle/123456789/44075
 
Language en_US
 
Rights <img src='http://nopr.niscair.res.in/image/cc-license-sml.png'> <a href='http://creativecommons.org/licenses/by-nc-nd/2.5/in' target='_blank'>CC Attribution-Noncommercial-No Derivative Works 2.5 India</a>
 
Publisher NISCAIR-CSIR, India
 
Source IJC-A Vol.32A(12) [December 1993]