Synthesis and characterisation of alkali metal oxothiovanadates(V)
IR@NISCAIR: CSIR-NISCAIR, New Delhi - ONLINE PERIODICALS REPOSITORY (NOPR)
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Title |
Synthesis and characterisation of alkali metal oxothiovanadates(V)
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Creator |
Bhaumik, B B
Ghosh, S |
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Description |
1079-1080
Oxothiovanadates of the types M<sup>1</sup>VO<sub>2</sub>S.H<sub>2</sub>O (where M = K<sup>+</sup>, Rb<sup>+</sup> and Na<sup>+</sup>) and NaVOS<sub>2</sub>.2H<sub>2</sub>O have been isolated and characterised. The TGA data reveal loss of H<sub>2</sub>S from these compounds. The complexes of the type M<sup>1</sup>VO<sub>2</sub>S.H<sub>2</sub>O (where M = K<sup>+</sup> & Rb<sup>+</sup>) yield MV<sub>3</sub>O<sub>8</sub>S and M<img src='http://www.niscair.res.in/jinfo/1bythree.gif' border=0>VO<sub>3</sub> on heating. The IR data reveal the presence of V = O and V = S bonds. The X-ray powder patterns are also reported. |
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Date |
2018-03-26T08:35:30Z
2018-03-26T08:35:30Z 1993-12 |
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Type |
Article
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Identifier |
0975-0975(Online); 0376-4710(Print)
http://nopr.niscair.res.in/handle/123456789/44078 |
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Language |
en_US
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Rights |
<img src='http://nopr.niscair.res.in/image/cc-license-sml.png'> <a href='http://creativecommons.org/licenses/by-nc-nd/2.5/in' target='_blank'>CC Attribution-Noncommercial-No Derivative Works 2.5 India</a>
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Publisher |
NISCAIR-CSIR, India
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Source |
IJC-A Vol.32A(12) [December 1993]
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