CSIR Central

Synthesis and characterisation of alkali metal oxothiovanadates(V)

IR@NISCAIR: CSIR-NISCAIR, New Delhi - ONLINE PERIODICALS REPOSITORY (NOPR)

View Archive Info
 
 
Field Value
 
Title Synthesis and characterisation of alkali metal oxothiovanadates(V)
 
Creator Bhaumik, B B
Ghosh, S
 
Description 1079-1080
Oxothiovanadates of the types M<sup>1</sup>VO<sub>2</sub>S.H<sub>2</sub>O (where M = K<sup>+</sup>, Rb<sup>+</sup> and Na<sup>+</sup>) and NaVOS<sub>2</sub>.2H<sub>2</sub>O have been isolated and characterised. The TGA data reveal loss of H<sub>2</sub>S from these compounds. The complexes of the type M<sup>1</sup>VO<sub>2</sub>S.H<sub>2</sub>O (where M = K<sup>+</sup> & Rb<sup>+</sup>) yield MV<sub>3</sub>O<sub>8</sub>S and M<img src='http://www.niscair.res.in/jinfo/1bythree.gif' border=0>VO<sub>3</sub> on heating. The IR data reveal the presence of V = O and V = S bonds. The X-ray powder patterns are also reported.
 
Date 2018-03-26T08:35:30Z
2018-03-26T08:35:30Z
1993-12
 
Type Article
 
Identifier 0975-0975(Online); 0376-4710(Print)
http://nopr.niscair.res.in/handle/123456789/44078
 
Language en_US
 
Rights <img src='http://nopr.niscair.res.in/image/cc-license-sml.png'> <a href='http://creativecommons.org/licenses/by-nc-nd/2.5/in' target='_blank'>CC Attribution-Noncommercial-No Derivative Works 2.5 India</a>
 
Publisher NISCAIR-CSIR, India
 
Source IJC-A Vol.32A(12) [December 1993]