Kinetics and mechanism of palladium(II) catalysed oxidation of some hydroxyacids by N-bromosuccinimide in perchloric acid medium
IR@NISCAIR: CSIR-NISCAIR, New Delhi - ONLINE PERIODICALS REPOSITORY (NOPR)
View Archive Info| Field | Value | |
| Title |
Kinetics and mechanism of palladium(II) catalysed oxidation of some hydroxyacids by N-bromosuccinimide in perchloric acid medium
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| Creator |
Saxena, Rashmi
Upadhyay, S K |
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| Description |
1060-1063
The kinetics of oxidation of palladium(II) catalysed oxidation of some hydroxyacids, viz, malic, citric and tartaric acids by N- bromosuccinimide have been studied in perchloric acid medium in the presence of mercuric acetate. A first order dependence of rate each in [oxidant] and [catalyst] has been observed. The order of reaction in substrate decreases at higher [substrate]. A retarding effect of [H<sup>+</sup>] on the rate has also been observed. A suitable mechanism consistent with observed kinetic data is proposed and discussed. |
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| Date |
2018-03-26T08:42:27Z
2018-03-26T08:42:27Z 1993-12 |
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| Type |
Article
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| Identifier |
0975-0975(Online); 0376-4710(Print)
http://nopr.niscair.res.in/handle/123456789/44082 |
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| Language |
en_US
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| Rights |
<img src='http://nopr.niscair.res.in/image/cc-license-sml.png'> <a href='http://creativecommons.org/licenses/by-nc-nd/2.5/in' target='_blank'>CC Attribution-Noncommercial-No Derivative Works 2.5 India</a>
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| Publisher |
NISCAIR-CSIR, India
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| Source |
IJC-A Vol.32A(12) [December 1993]
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