Kinetics and mechanism of oxidation of dimethylformamide (DMF) by diperiodato-nickelate(IV) (DPN) in aqueous alkaline medium
IR@NISCAIR: CSIR-NISCAIR, New Delhi - ONLINE PERIODICALS REPOSITORY (NOPR)
View Archive Info| Field | Value | |
| Title |
Kinetics and mechanism of oxidation of dimethylformamide (DMF) by diperiodato-nickelate(IV) (DPN) in aqueous alkaline medium
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| Creator |
Hugar, G H
Nandibewoor, S T |
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| Description |
1056-1059
The title reaction is first order in [diperiodatonickelate(IV)] (DPN) and fractional order both in [dimethylformamide] (DMF) and [OH<sup>-</sup>]. Periodate has a retarding effect on the reaction. Effects of added products, ionic strength, dielectric constant of the reaction medium and temperature on the reaction have been examined. A mechanism has been proposed with MPN [monoperiodatonickel-ate(IV)] as the active oxidant. |
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| Date |
2018-03-26T08:44:04Z
2018-03-26T08:44:04Z 1993-12 |
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| Type |
Article
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| Identifier |
0975-0975(Online); 0376-4710(Print)
http://nopr.niscair.res.in/handle/123456789/44083 |
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| Language |
en_US
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| Rights |
<img src='http://nopr.niscair.res.in/image/cc-license-sml.png'> <a href='http://creativecommons.org/licenses/by-nc-nd/2.5/in' target='_blank'>CC Attribution-Noncommercial-No Derivative Works 2.5 India</a>
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| Publisher |
NISCAIR-CSIR, India
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| Source |
IJC-A Vol.32A(12) [December 1993]
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