Synthesis and characterization of hydridocarbonylbis(triphenylphosphine) ruthenium(II) dialkyldithiophosphates
IR@NISCAIR: CSIR-NISCAIR, New Delhi - ONLINE PERIODICALS REPOSITORY (NOPR)
View Archive Info| Field | Value | |
| Title |
Synthesis and characterization of hydridocarbonylbis(triphenylphosphine) ruthenium(II) dialkyldithiophosphates
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| Creator |
Jain, VimaI K
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| Description |
1034-1036
Complexes of the type [RuH{SSP(OR)<sub>2</sub>}(CO(PPh<sub>3</sub>)<sub>2</sub>] (R = Et, Pr<em><sup>n</sup></em>, Pr<em><sup>i</sup></em>, Bu<em><sup>n</sup></em>, Bu<em><sup>i</sup></em>, Bu<em><sup>s</sup></em>) have been prepared by the reaction of [RuHCI(CO)(PPh<sub>3</sub>)<sub>3 </sub>with ammonium salt of the dialkyldithiophosphoric acid. These complexes have been characterized by elemental analyses and IR and NMR (<sup>1</sup>H and <sup>31</sup>P) data. The <sup>1</sup>H NMR data indicate the phosphine ligands are <em>cis </em>to hydride. |
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| Date |
2018-03-26T08:58:42Z
2018-03-26T08:58:42Z 1993-12 |
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| Type |
Article
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| Identifier |
0975-0975(Online); 0376-4710(Print)
http://nopr.niscair.res.in/handle/123456789/44088 |
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| Language |
en_US
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| Rights |
<img src='http://nopr.niscair.res.in/image/cc-license-sml.png'> <a href='http://creativecommons.org/licenses/by-nc-nd/2.5/in' target='_blank'>CC Attribution-Noncommercial-No Derivative Works 2.5 India</a>
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| Publisher |
NISCAIR-CSIR, India
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| Source |
IJC-A Vol.32A(12) [December 1993]
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