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A novel electroluminescent device based on a reduced graphene oxide wrapped phosphor (ZnS:Cu,Al) and hexagonal-boron nitride for high-performance luminescence

IR@NPL: CSIR-National Physical Laboratory, New Delhi

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Title A novel electroluminescent device based on a reduced graphene oxide wrapped phosphor (ZnS:Cu,Al) and hexagonal-boron nitride for high-performance luminescence
 
Creator Gupta, Bipin Kumar
Singh, Satbir
Kedawat, Garima
-, Kanika
Kumar, Pawan
Gangwar, Amit Kumar
Narayanan, Tharangattu N.
Marti, Angel A.
Vajtai, Robert
Ajayane, P. M.
 
Subject Chemistry
Materials Science
Applied Physics/Condensed Matter
Nanoscience/ Nanotechnology
 
Description Reduced graphene oxide (rGO) has recently emerged as a very promising family of exotic carbon material with augmented performance in electronic and optoelectronic devices. Herein, we report an efficient and novel inorganic electroluminescent device geometry, where a new phosphor composite, reduced graphene oxide wrapped ZnS:Cu, Al, acts as an active emitting layer and an exfoliated hexagonal boron nitride (h-BN) as a dielectric layer. The roles of rGO in the active layer as a conductive support and local electric field enhancing agent are attributed to its wrinkles being unraveled compared with other carbon exotic nano-forms such as carbon nanotubes, graphite, charcoal and activated carbon, which significantly improves the brightness of the device (similar to 50 cd m (2) for 0.50 wt% rGO/ZnS: Cu, Al at 10 kHz and 110 V with an external quantum efficiency of similar to 6.3% +/- 0.1% and current efficiency of similar to 0.81 +/- 0.09 cd A(-1)). This new and facile strategy to construct the luminescent devices could be a paradigm shift towards cost effective, highly stable in air (for several days) and energy efficient next generation display devices.
 
Publisher Royal Society of Chemistry
 
Date 2017-04
 
Type Article
PeerReviewed
 
Format application/pdf
 
Identifier http://npl.csircentral.net/2610/1/A%20novel%20electroluminescent%20device.pdf
Gupta, Bipin Kumar and Singh, Satbir and Kedawat, Garima and -, Kanika and Kumar, Pawan and Gangwar, Amit Kumar and Narayanan, Tharangattu N. and Marti, Angel A. and Vajtai, Robert and Ajayane, P. M. (2017) A novel electroluminescent device based on a reduced graphene oxide wrapped phosphor (ZnS:Cu,Al) and hexagonal-boron nitride for high-performance luminescence. Nanoscale, 9 (15). pp. 5002-5008. ISSN 2040-3364
 
Relation http://npl.csircentral.net/2610/