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Emerging photoluminescence from bilayer large-area 2D MoS2 films grown by pulsed laser deposition on different substrates

IR@NPL: CSIR-National Physical Laboratory, New Delhi

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Title Emerging photoluminescence from bilayer large-area 2D MoS2 films grown by pulsed laser deposition on different substrates
 
Creator Barvat, Arun
Prakash, Nisha
Satpati, Biswarup
Singha, Shib Shankar
Kumar, Gaurav
Singh, Dilip K.
Dogra, Anjana
Khanna, Suraj P.
Singha, Achintya
Pal, Prabir
 
Subject Applied Physics/Condensed Matter
 
Description We report the growth of continuous large area bilayer films of MoS2 on different substrates by pulsed laser deposition (PLD). The growth parameters for PLD were modified in such a way that results in bilayer 2D-MoS2 films on both c-Al2O3 (0001) (sapphire) and SiO2/Si (SO) substrates. The bilayer large area crystalline nature of growth in the 2 H-phase is determined by Raman spectroscopy. Cross-sectional transmission electron microscopy confirms the distinct thinnest ordered layered structure of MoS2. Chemical analysis reveals an almost stoichiometric 2 H-phase on both the substrates. The photoluminescence intensities of both the films match very well with those of the corresponding exfoliated flakes, as well as chemical vapor deposited (CVD) films as reported in the literature. The in-situ post growth annealing with optimal film thickness acts as a solid phase epitaxy process which provides continuous crystalline layers with a smooth interface and regulates the photoluminescence properties. In contrast, the PLD grown MoS2 monolayer shows poor crystalline quality and non-uniform coverage compared to that with the exfoliated and CVD grown films.
 
Publisher American Institute of Physics
 
Date 2017-07-07
 
Type Article
PeerReviewed
 
Format application/pdf
 
Identifier http://npl.csircentral.net/2690/1/Emerging%20photoluminescence%20from%20bilayer%20large-area%202D%20MoS2%20films%20grown%20by%20pulsed%20laser%20deposition%20on%20different%20substrates.pdf
Barvat, Arun and Prakash, Nisha and Satpati, Biswarup and Singha, Shib Shankar and Kumar, Gaurav and Singh, Dilip K. and Dogra, Anjana and Khanna, Suraj P. and Singha, Achintya and Pal, Prabir (2017) Emerging photoluminescence from bilayer large-area 2D MoS2 films grown by pulsed laser deposition on different substrates. Journal of Applied Physics , 122 (1). 015304-1-015304-9. ISSN 0021-8979
 
Relation http://npl.csircentral.net/2690/