N-Arylation of heterocycles by mixed ligand transition metal complexes under mild conditions
IR@NISCAIR: CSIR-NISCAIR, New Delhi - ONLINE PERIODICALS REPOSITORY (NOPR)
View Archive Info| Field | Value | |
| Title |
N-Arylation of heterocycles by mixed ligand transition metal complexes under mild conditions
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| Creator |
Hegade, S S
Gaikwad, G A Mulik, G N |
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| Subject |
Quinazolinone Schiff base
Mixed ligand transition metal complex N-arylation Heterocycles |
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| Description |
1304-1309
Mixed ligand transition metal complexes [M(L)(PPh<sub>3</sub>)<sub>2</sub>]X<sub>2</sub> 1-4 where L- 2-phenyl, 3-benzoylamino-1,2-dihydroquinazolin-4(3<em>H</em>)-one (PBADQ), where M is Co, Ni, Cu, Zn and X is Cl have been synthesized and characterized by elemental analysis, IR, NMR spectral studies and their role as catalyst in N-arylation of indole and isatin with aryl halides. It has been observed that all the complexes worked as efficient catalysts, especially [Ni(L)(PPh<sub>3</sub>)<sub>2</sub>]Cl<sub>2 </sub>complex <strong>2</strong> is found to be most suitable for N-arylation of indole and isatin. |
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| Date |
2018-10-11T10:35:35Z
2018-10-11T10:35:35Z 2018-10 |
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| Type |
Article
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| Identifier |
0975-0983(Online); 0376-4699(Print)
http://nopr.niscair.res.in/handle/123456789/45177 |
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| Language |
en_US
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| Rights |
<img src='http://nopr.niscair.res.in/image/cc-license-sml.png'> <a href='http://creativecommons.org/licenses/by-nc-nd/2.5/in' target='_blank'>CC Attribution-Noncommercial-No Derivative Works 2.5 India</a>
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| Publisher |
NISCAIR-CSIR, India
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| Source |
IJC-B Vol.57B(10) [October 2018]
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