Nanomolar level detection of explosive and pollutant TNP by fluorescent aryl naphthalene sulfones: DFT study, in vitro detection and portable prototype fabrication
IR@CMERI: CSIR- Central Mechanical Engineering Research Institute (CMERI), Durgapur
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| Title |
Nanomolar level detection of explosive and pollutant TNP by fluorescent aryl naphthalene sulfones: DFT study, in vitro detection and portable prototype fabrication
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| Creator |
Ghosh, Pritam
Das, Joyee Basak, Amit Mukhopadhyay, Subhra Kanti Banerjee, Priyabrata |
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| Subject |
Chemistry
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| Description |
Luminescent Aryl Naphthalene Sulfones have been prepared via Garratt-Braverman cyclization of γ-substituted bis-propargyl sulfones for explosive and pollutant 2,4,6-Tri nitrophenol (TNP) recognition in aqueous medium by fluorescence quenching. The quenching can be explained through AIE-ACQ-RET-ICT based mechanisms. In vitro detection of TNP has been performed inside pollen cells. In real time stepping, paper strip and pocket solution kit has been fabricated for on spot detection of TNP. Moreover as an analytical application TNP has been detected from several surface water specimens collected throughout West Bengal, India. The limit of detection has been found as low as 10 nM together with quenching constant as 6.8 × 105 M−1, which is even superior to the recently published sensor materials.
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| Publisher |
Elsevier
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| Date |
2017-11
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| Type |
Article
PeerReviewed |
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| Identifier |
Ghosh, Pritam and Das, Joyee and Basak, Amit and Mukhopadhyay, Subhra Kanti and Banerjee, Priyabrata (2017) Nanomolar level detection of explosive and pollutant TNP by fluorescent aryl naphthalene sulfones: DFT study, in vitro detection and portable prototype fabrication. Sensors and Actuators B: Chemical, 251. pp. 985-992.
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| Relation |
http://cmeri.csircentral.net/489/
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