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Synthesis and structural characterization of some organoboron complexes with nitrogen donor azomethines

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Title Synthesis and structural characterization of some organoboron complexes with nitrogen donor azomethines
 
Creator Saxena, (Miss) Chitra
Fahmi, N
Singh, R V
 
Description 963-965
A few organoboron complexes of nitrogen and sulphur/oxygen containing ligands having <img src='http://www.niscair.res.in/jinfo/equation93.gif' border=0>H and <img src='http://www.niscair.res.in/jinfo/equation94.gif' border=0>H donor systems have been synthesised and characterized on the basis of molecular weight determination, conductance measurements, IR, <sup>1</sup>H NMR, <sup>13</sup>C NMR and <sup>11</sup>B NMR spectral studies. The unimolecular and bimolecular reactions between phenylboronic acid and the ligands under investigation have yielded non-electrolytic complexes of the type PhB(OH)(<img src='http://www.niscair.res.in/jinfo/equation93.gif' border=0>), PhB(OH)(<img src='http://www.niscair.res.in/jinfo/equation94.gif' border=0>), PhB(<img src='http://www.niscair.res.in/jinfo/equation93.gif' border=0>)<sub>2</sub> and PhB(<img src='http://www.niscair.res.in/jinfo/equation94.gif' border=0>)<sub>2</sub> respectively. A stable tetracoordinated environment around the boron atom has been assigned.
 
Date 2019-03-18T04:24:54Z
2019-03-18T04:24:54Z
1992-12
 
Type Article
 
Identifier 0975-0975(Online); 0376-4710(Print)
http://nopr.niscair.res.in/handle/123456789/45971
 
Language en_US
 
Rights <img src='http://nopr.niscair.res.in/image/cc-license-sml.png'> <a href='http://creativecommons.org/licenses/by-nc-nd/2.5/in' target='_blank'>CC Attribution-Noncommercial-No Derivative Works 2.5 India</a>
 
Publisher NISCAIR-CSIR, India
 
Source IJC-A Vol.31A(12) [December 1992]