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Low reflecting hierarchically textured silicon by silver assisted chemical etching for potential solar cell application

IR@NPL: CSIR-National Physical Laboratory, New Delhi

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Title Low reflecting hierarchically textured silicon by silver assisted chemical etching for potential solar cell application
 
Creator Singh, Prashant
Srivastava, Sanjay K.
Prajapati, Vijay
Sivaiah, B.
Rauthan, C. M. S.
Singh, P. K.
 
Subject Physical Chemistry/Chemical Physics
 
Description Present study reports fabrication of silicon nanowires over micro-textured Si substrates. Silver assisted electroless chemical etching route has been adopted for fabrication of the nanowires. Influence of HF concentration on the formation kinetics has been investigated by using scanning electron microscopy. The hierarchical binary structures have been able to reduce solar weighted reflectance (SWR) to < 3% in broad spectral range (300-1100 nm), from 38% SWR of the polished silicon without any additional coating. Such reduction in reflectivity is obtained for < 1 mu m nanowires length. It is observed that at relatively lower concentration of HF the nanowires are preferably formed only in <100> direction. However, with increase in the concentration, etching in both <100> and non-<100> directions such as <111> also occurs on the micro-pyramids of similar dimensions and results in the binary structures with slanted silicon nanowires on 3-dimansional micro-pyramids.
 
Publisher Elsevier
 
Date 2018
 
Type Article
PeerReviewed
 
Format application/pdf
 
Identifier http://npl.csircentral.net/4006/1/Low%20reflecting%20hierarchically%20textured.pdf
Singh, Prashant and Srivastava, Sanjay K. and Prajapati, Vijay and Sivaiah, B. and Rauthan, C. M. S. and Singh, P. K. (2018) Low reflecting hierarchically textured silicon by silver assisted chemical etching for potential solar cell application. Materials Today: Proceedings , 5 (11). pp. 23258-23267. ISSN 2214-7853
 
Relation http://npl.csircentral.net/4006/