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Study of Phosphorus Doped Micro/Nano Crystalline Silicon Films Deposited by Filtered Cathodic Vacuum Arc Technique

IR@NPL: CSIR-National Physical Laboratory, New Delhi

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Title Study of Phosphorus Doped Micro/Nano Crystalline Silicon Films Deposited by Filtered Cathodic Vacuum Arc Technique
 
Creator Kesarwani, Ajay Kumar
Panwar, O. S.
Tripathi, R. K.
Dalai, M. K.
Chockalingam, Sreekumar
 
Subject Physical Chemistry
Materials Science
 
Description Phosphorus doped micro/nano crystalline silicon thin films have been deposited by the filtered cathodic vacuum arc technique at different substrate temperatures (T-s) ranging from room temperature (RT) to 350 degrees C. The films have been characterized by X-ray diffraction (XRD), Raman spectroscopy, scanning electron microscopy, secondary ion mass spectroscopy, dark conductivity (sigma(D)), activation energy (Delta E) and optical band gap (E-g). The XRD patterns show that the RT grown film is amorphous in nature but high T-s (225 and 350 degrees C) deposited films have a crystalline structure with (111) and (220) crystal orientation. The crystallite size of the higher T-s grown silicon films evaluated was between 17 to 31 nm. Raman spectra reveal the amorphous nature of the film deposited at RT whereas higher T-s deposited films show a higher crystalline nature. The crystalline volume fraction of the silicon film deposited at higher T-s was estimated as 65.7% and 74.4%. The values of sigma(D), Delta E and E-g of the silicon films deposited at different T-s were found to be in the range of 8.84 x 10(-4) - 0.98 ohm(-1)cm(-1), 0.06 - 0.31 eV and 1.31-1.93 eV, respectively. A n-type nc-Si/p-type c-Si heterojunction diode was fabricated which showed the diode ideality factor between 1.1 to 1.5.
 
Publisher Elsevier
 
Date 2017-07
 
Type Article
PeerReviewed
 
Format application/pdf
 
Identifier http://npl.csircentral.net/2891/1/Study%20of%20Phosphorus%20Doped%20Micro%20Nano%20Crystalline%20Silicon%20Films%20Deposited%20by%20Filtered%20Cathodic%20Vacuum%20Arc%20Technique.pdf
Kesarwani, Ajay Kumar and Panwar, O. S. and Tripathi, R. K. and Dalai, M. K. and Chockalingam, Sreekumar (2017) Study of Phosphorus Doped Micro/Nano Crystalline Silicon Films Deposited by Filtered Cathodic Vacuum Arc Technique. Sustainable Cities and Society, 9 (4). pp. 473-481. ISSN 1876-990X
 
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