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High surface area bio-waste based carbon as a superior electrode for vanadium redox flow battery

IR@CECRI: CSIR-Central Electrochemical Research Institute, Karaikudi

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Title High surface area bio-waste based carbon as a superior electrode for vanadium redox flow battery
 
Creator Maharjan, M.
Bhattarai, A.
Ulaganathan, M.
Wai, N.
Oo, M.O.
Wang, J.Y.
Lim, T.M.
 
Subject Electrochemical Power Sources
 
Description Activated carbon (AC) with high surface area (1901 m2 g�1) is synthesized from low cost bio-waste orange (Citrus sinensis) peel for vanadium redox flow battery (VRB). The composition, structure and electrochemical properties of orange peel derived AC (OP-AC) are characterized by elemental analyzer, field emission-scanning electron microscopy, X-ray diffraction, Raman spectroscopy, X-ray photoelectron spectroscopy, cyclic voltammetry (CV), and electrochemical impedance spectroscopy. CV results show that OP-AC coated bipolar plate demonstrates improved electro-catalytic activity in both positive and negative side redox couples than the pristine bipolar plate electrode and this is ascribed to the high surface area of OP-AC which provides effective electrode area and better contact between the porous electrode and bipolar plate. Consequently, the performance of VRB in a static cell shows higher energy efficiency for OP-AC electrode than the pristine electrode at all current densities tested. The results suggest the OP-AC to be a promising electrode for VRB applications and can be incorporated into making conducting plastics electrode to lower the VRB cell stack weight and cost.
 
Publisher Elsevier B.V.
 
Date 2017
 
Type Article
PeerReviewed
 
Format application/pdf
 
Identifier http://cecri.csircentral.net/3208/1/121-2017.pdf
Maharjan, M. and Bhattarai, A. and Ulaganathan, M. and Wai, N. and Oo, M.O. and Wang, J.Y. and Lim, T.M. (2017) High surface area bio-waste based carbon as a superior electrode for vanadium redox flow battery. Journal of Power Sources, 362. pp. 50-56. ISSN 0378-7753
 
Relation http://www.elsevier.com/locate/jpowsour
http://cecri.csircentral.net/3208/