Enhanced electrochemical performance of lithium rich layered cathode materials by Ca2+ substitution
IR@CECRI: CSIR-Central Electrochemical Research Institute, Karaikudi
View Archive Info| Field | Value | |
| Title |
Enhanced electrochemical performance of lithium rich layered cathode materials by Ca2+ substitution
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| Creator |
Laisa, C.P.
Ramesha, R.N. Ramesha, K. |
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| Subject |
Lithium batteries
Electrochemical Power Sources |
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| Description |
The poor cycling stability and large voltage decay in Li-rich cathode materials is related to the layer to
spinel structural transformation. It is understood that the ease of structural transformation is correlated
to the amount of oxygen gas released during the
first charge above 4.5 V. So one of the effective strategy to improve the electrochemical properties is by suppressing oxygen evolution through stabilizing oxygen
radical intermediates by tuning metal-oxygen bond characteristics such as covalency, bond energy,
iconicity, etc. through cation substitutions in Li rich phases. In this work we report that small amount of
Ca substitution in Li layers of Li rich phases, Li1.2-2xCaxCo0.13Ni0.13Mn0.54O2 (x = 0.005) improves the
electrochemical cycling stability as well as the rate capability. With x = 0.005 calcium substitution, the
initial coulombic efficiency increased from 70% (for the pristine) to 83% and the capacity retention is
improved from 71% to 87% after 100 cycles. Similarly Ca doping improves the rate capability especially at
higher rates. The improved electrochemical performance of the Ca doped Li-rich cathode can be attributed to the
fine-tuning of the crystal-chemical aspects manifested through enhanced structural stability and increased interlayer distance
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| Publisher |
Elsevier
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| Date |
2017-10-05
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| Type |
Article
PeerReviewed |
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| Format |
application/pdf
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| Identifier |
http://cecri.csircentral.net/3236/1/188-2017.pdf
Laisa, C.P. and Ramesha, R.N. and Ramesha, K. (2017) Enhanced electrochemical performance of lithium rich layered cathode materials by Ca2+ substitution. Electrochimica Acta, 256. pp. 10-18. ISSN 0013-4686 |
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| Relation |
http://www.elsevier.com/locate/electacta
http://cecri.csircentral.net/3236/ |
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