Silica template assisted synthesis of ordered mesoporous be MnO2 nanostructures and their performance evaluation as negative electrode in Li-ion batteries
IR@CECRI: CSIR-Central Electrochemical Research Institute, Karaikudi
View Archive Info| Field | Value | |
| Title |
Silica template assisted synthesis of ordered mesoporous be MnO2 nanostructures and their performance evaluation as negative electrode in Li-ion batteries
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| Creator |
Ette, P.M.
Selvakumar, K. Senthil Kumar, S.M. Ramesha, K. |
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| Subject |
Fuel Cells
Lithium batteries Electrochemical Power Sources |
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| Description |
In the pursuit of high capacity anode materials transition metal oxides have paid great deal of attention.
However poor electronic conductivity, high discharge potential and volume change during electrochemical cycling hinders their practical applications. In this report, we synthesize the well-ordered
mesoporous b-MnO2 phases (pyrolusite structure) using SBA-15 and MCM-48 templates. The product
derived from SBA-15, designated as SBA-MnO2 has interconnected nanorod like morphology, whereas
the product derived from MCM-48, designated as MCM-MnO2 exhibits open cage/bowl like morphology.
The products are characterized by XRD, FTIR, FESEM, TEM, XPS, BET surface area measurements. Further,
electrochemical studies are carried out to investigate their application as anode material for Li-ion
batteries. Galvanostatic cycling shows initial discharge capacity of ~1500 mAhg�1 and 1750 mAhg�1
respectively for SBA-MnO2 and MCM-MnO2. After 100 charge-discharge cycles, MCM-MnO2 electrode
exhibits capacity 345 mAhg�1 and SBA-MnO2 shows a capacity of 245 mAhg�1
. Though both the
materials show capacity fading upon long cycling, their performance is better compared to other MnO2
nanostructures reported in the literature. They also exhibit good rate capability indicating that mesoporous MnO2 materials reported here can be potential candidate for Li-ion storage
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| Publisher |
Elsevier
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| Date |
2018-10-01
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| Type |
Article
PeerReviewed |
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| Format |
application/pdf
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| Identifier |
http://cecri.csircentral.net/3246/1/285-2018.pdf
Ette, P.M. and Selvakumar, K. and Senthil Kumar, S.M. and Ramesha, K. (2018) Silica template assisted synthesis of ordered mesoporous be MnO2 nanostructures and their performance evaluation as negative electrode in Li-ion batteries. Electrochimica Acta, 282. pp. 532-539. ISSN 0013-4686 |
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| Relation |
http://www.elsevier.com/locate/electacta
http://cecri.csircentral.net/3246/ |
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