Structural, optical and electrical description of camphor sulfonic acid diped poly (2, 5-dimetoxyaniline) thin film
IR@NML: CSIR-National Metallurgical Laboratory, Jamshedpur
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Title |
Structural, optical and electrical description of camphor sulfonic acid diped poly (2, 5-dimetoxyaniline) thin film
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Creator |
Dayana, A M
Williams, R V |
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Subject |
Electronic and Magnetic Properties
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Description |
Emeraldine Base Poly (2, 5-dimethoxyaniline) has been synthesized by oxidative polymerization using ammonium persulfate as an oxidant. Protonated Poly (2, 5-dimethoxy aniline) have been achieved by doping with Camphor sulfonic acid with different weight ratio as 1: x (x=0, 0.25, 0.5, 1). Poly (2, 5-dimethoxyaniline) Emeraldine Salt was spin coated as thin film by using m-cresol solvent cum secondary dopant. Camphor sulfonic acid doped Poly (2, 5-dimethoxy aniline) thin films were characterized by UV-V spectrophotometer, Fourier Transform Infrared spectroscopy, X-RAYDiffraction, PLfor the analysis of band gap, chemical composition, structural confirmation and electronic transition. SEM micrograph images exposed the changes of plate structure to rod for Poly (2, 5-dimethoxyaniline) thin films. The band gap of undoped Poly (2, 5-dimethoxyaniline) thin film was found as 3.67eV. The level of dopant was found to influence the band gap and the DC conductivity of Camphor sulfonic acid doped Poly (2, 5-dimethoxyaniline) thin films.
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Publisher |
Indian Journals
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Date |
2018
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Type |
Article
PeerReviewed |
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Relation |
https://doi.org/https://www.indianjournals.com/ijor.aspx?target=ijor:jmms&volume=60&issue=3&article=003
http://eprints.nmlindia.org/8033/ |
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Identifier |
Dayana, A M and Williams, R V (2018) Structural, optical and electrical description of camphor sulfonic acid diped poly (2, 5-dimetoxyaniline) thin film. Journal of Metallurgy and Materials Science, 60(3) . pp. 149-155.
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