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Graphene Quantum Dots Derived from Carbon Fibers

IR@NPL: CSIR-National Physical Laboratory, New Delhi

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Title Graphene Quantum Dots Derived from Carbon Fibers
 
Creator Peng, Juan
Gao, Wei
Gupta, Bipin Kumar
Liu, Zheng
Romero-Aburto , Rebeca
Ge, Liehui
Song, Li
Alemany, Lawrence B.
Zhan, Xiaobo
Gao, Guanhui
Vithayathil, Sajna Antony
Kaipparettu, Benny Abraham
Marti, Angel A.
Hayashi, Takuya
Zhu, Jun-Jie
Ajayan, Pulickel M.
 
Subject Physical Chemistry
Materials Science
Applied Physics/Condensed Matter
Nanoscience/ Nanotechnology
 
Description Graphene quantum dots (GQDs), which are edge-bound nanometer-size graphene pieces, have fascinating optical and electronic properties. These have been synthesized either by nanolithography or from starting materials such as graphene oxide (GO) by the chemical breakdown of their extended planar structure, both of which are multistep tedious processes. Here, we report that during the acid treatment and chemical exfoliation of traditional pitch-based carbon fibers, that are both cheap and commercially available, the stacked graphitic submicrometer domains of the fibers are easily broken down, leading to the creation of GQDs with different size distribution in scalable amounts. The as-produced GQDs, in the size range of 1-4 nm, show two-dimensional morphology, most of which present zigzag edge structure, and are 1-3 atomic layers thick. The photoluminescence of the GQDs can be tailored through varying the size of the GQDs by changing process parameters. Due to the luminescence stability, nanosecond lifetime, biocompatibility, low toxicity, and high water solubility, these GQDs are demonstrated to be excellent probes for high contrast bioimaging and biosensing applications.
 
Publisher American Chemical Society
 
Date 2018-02
 
Type Article
PeerReviewed
 
Format application/pdf
 
Identifier http://npl.csircentral.net/4051/1/dec%202016%20.pdf
Peng, Juan and Gao, Wei and Gupta, Bipin Kumar and Liu, Zheng and Romero-Aburto , Rebeca and Ge, Liehui and Song, Li and Alemany, Lawrence B. and Zhan, Xiaobo and Gao, Guanhui and Vithayathil, Sajna Antony and Kaipparettu, Benny Abraham and Marti, Angel A. and Hayashi, Takuya and Zhu, Jun-Jie and Ajayan, Pulickel M. (2018) Graphene Quantum Dots Derived from Carbon Fibers. Nano Letters, 12 (2). pp. 844-849. ISSN 1530-6984
 
Relation http://npl.csircentral.net/4051/