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Tb3+ and Eu3+ Doped Zinc Phosphate Glasses for Solid State Lighting Applications

IR@NPL: CSIR-National Physical Laboratory, New Delhi

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Title Tb3+ and Eu3+ Doped Zinc Phosphate Glasses for Solid State Lighting Applications
 
Creator Sharma, Anshul Kumar
Mahajan, Aman
Kumar, Subodh
Debnath, A. K.
Aswal, D. K.
 
Subject Chemistry
 
Description To investigate how central metal tunes the synergetic interactions between substituted metallo-phthalocyanine and single-walled carbon nanotubes in enhancing the gas sensing properties, a comparative study has been performed by varying the central metal ion in fluorinated metal phthalocyanines and single-walled carbon nanotube hybrid. Hybrids of metal(ii)-1,2,3,4,8,9,10,11,15,16,17,18-24,25-hexa-decafluoro-29H,31H-phthalocyanine/single-walled carbon nanotube (F16MPc/SWCNTs-COOH, where M = Co, Zn) have been synthesized through - stacking interactions using the solution route. Spectroscopic (FT-IR, UV-vis, XPS and Raman), electron microscopic (TEM and FE-SEM) and TGA investigations have confirmed the successful functionalization and interaction of SWCNTs-COOH with F16MPc. Parts per billion (ppb) level Cl-2-selective chemiresistive gas sensors have been fabricated on glass substrates with precoated gold electrodes by using these hybrids. The responses of various F16MPc/SWCNTs-COOH sensors have demonstrated the central metal ion-dependence in the sensitivity of Cl-2.
 
Publisher Royal Society of Chemistry
 
Date 2018
 
Type Article
PeerReviewed
 
Format application/pdf
 
Identifier http://npl.csircentral.net/3950/1/Tb%203%2B%20and%20Eu%203%2B%20Doped%20Zinc%20Phosphate.pdf
Sharma, Anshul Kumar and Mahajan, Aman and Kumar, Subodh and Debnath, A. K. and Aswal, D. K. (2018) Tb3+ and Eu3+ Doped Zinc Phosphate Glasses for Solid State Lighting Applications. RSC Advances , 8 (57). pp. 32719-32730. ISSN 2046-2069
 
Relation http://npl.csircentral.net/3950/