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Evaluation of Thermal Decomposition Characteristics and Kinetic Parameters of Melina Wood

IR@NML: CSIR-National Metallurgical Laboratory, Jamshedpur

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Title Evaluation of Thermal Decomposition Characteristics and Kinetic Parameters of Melina Wood
 
Creator Adeleke, A A
Odusote, J K
Lasode, O A
Ikubanni, P P
Malathi, M
Paswan, Dayanand
 
Subject Waste Utilization
Waste Recycling
Waste Management
Pyrometallurgy
 
Description The evaluation of thermal decomposition characteristics and kinetic parameters of melina wood were investigated. Proximate, ultimate and calorific value analyses of the melina wood were carried out based on standards. Melina wood was subjected to multiple heating rates (5–15oC/min) in thermogravimetric experiment. Two prominent isoconversional methods (Flynn-Wall-Ozawa and Starink) were adopted to obtain kinetic parameters from the non-isothermal thermogravimetric analysis curves. The ash, volatile matter and carbon contents of the melina were 2.15, 81.42 and 47.05%, respectively, while the calorific value was 18.72MJ/kg. The main devolatilization stage of melina ranged from 220oC to 350oC while 80% weight loss was obtained below 400oC. The activation energy varied between approximately 15 and 162kJ/mol as a function of degree of conversion. The pre-exponential factors varied between 1.60Eþ2 and 5.67 Eþ12/min. The decomposition kinetic mechanism of melina is concluded to be a multi-step reaction.
 
Publisher TAYLOR & FRANCIS LTD
 
Date 2019-08-06
 
Type Article
PeerReviewed
 
Format application/pdf
 
Identifier http://eprints.nmlindia.org/8076/1/adeleke2019.pdf
Adeleke, A A and Odusote, J K and Lasode, O A and Ikubanni, P P and Malathi, M and Paswan, Dayanand (2019) Evaluation of Thermal Decomposition Characteristics and Kinetic Parameters of Melina Wood. Biofuels (IF-1.130). pp. 1-7.
 
Relation https://doi.org/10.1080/17597269.2019.1646541
http://eprints.nmlindia.org/8076/