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Crystal growth, optical and thermal studies of nonlinear optical gamma-glycine single crystal grown from lithium nitrate

IR@NPL: CSIR-National Physical Laboratory, New Delhi

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Title Crystal growth, optical and thermal studies of nonlinear optical gamma-glycine single crystal grown from lithium nitrate
 
Creator Kumar, R. Ashok
Vizhi, R. Ezhil
Sivakumar, N
Vijayan, N.
Babu, D. Rajan
 
Subject Optics
 
Description Single crystals of the nonlinear material gamma-glycine have been grown in the presence of lithium nitrate by slow-evaporation method. Structural characterization of the grown crystals was carried out by powder and single crystal X-ray diffraction (XRD) methods and it is observed that the samples crystallize in hexagonal system with non-centrosymmetric space groups. The modes of vibrations of different molecular groups present in glycine have been identified by spectral analyses. UV-visible transmittance study was performed to analyze optical transparency of gamma-glycine crystals and found that the crystal was transparent in the entire visible-NIR region. Second harmonic generation (SHG) conversion efficiency has been estimated as 62 mV and the output power by the crystal was 1.72 times that of potassium dihydrogen phosphate (KDP) crystal. The thermal stability and decomposition of the sample have been studied by thermal analysis and if is observed that the gamma-glycine crystal have good thermal stability.
 
Publisher Elsevier
 
Date 2012
 
Type Article
PeerReviewed
 
Format application/pdf
 
Identifier http://npl.csircentral.net/3659/1/Crystal%20growth%2C%20optical%20and%20thermal%20studies.pdf
Kumar, R. Ashok and Vizhi, R. Ezhil and Sivakumar, N and Vijayan, N. and Babu, D. Rajan (2012) Crystal growth, optical and thermal studies of nonlinear optical gamma-glycine single crystal grown from lithium nitrate. Optik , 123. pp. 409-413. ISSN 0030-4026
 
Relation http://npl.csircentral.net/3659/