Directly grown Sr-Co layered double hydroxide (LDH) entangled two dimensional nanosheet film with superior performances
IR@NPL: CSIR-National Physical Laboratory, New Delhi
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Title |
Directly grown Sr-Co layered double hydroxide (LDH) entangled two dimensional nanosheet film with superior performances
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Creator |
Bailmare, Deepa B.
Deshmukh, Kavita A. Sivaraman, P. Peshwe, D. R. Gupta, Bipin Kumar Dhoble, S. J. Deshmukh, Abhay D. |
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Subject |
Electrochemistry
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Description |
Designing of electrode with electrochemically rich structure, outstanding mechanical robustness and high electrical conductivity remains a challenge. We report a design of entangled Sr-Co Layered double hydroxides (LDHs) two-dimensional structure for such electrode. The hierarchical electrode with entangled nanosheet exhibit high specific capacitance of 1415 F g(-1) at 5 A g(-1) current density, excellent rate capability, high energy (12.28Whkg(-1)) and power density (567.788 W kg(-1)) and outstanding stability (80% capacity retention over 5000 cycles). The asymmetric device cell of Sr-Co LDH/ACC gives high energy density (27.78 Whkg-1) and power density (499.96Wkg-1) with cyclic performance of 1000 cycles with 95.24% capacitance retention. Further, we provide a detailed analysis of the various electrolyte environment experienced by the electrode and their effect on electrochemical properties. We pick out three different electrolytes; LiOH, NaOH, KOH and show that both selected electrolyte and metal combination for LDHs paves the way for outstanding electrochemical performance.
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Publisher |
Elsevier
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Date |
2019-12-20
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Type |
Article
PeerReviewed |
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Format |
application/pdf
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Identifier |
http://npl.csircentral.net/4155/1/Directly%20grown%20SreCo%20layered%20double%20hydroxide.pdf
Bailmare, Deepa B. and Deshmukh, Kavita A. and Sivaraman, P. and Peshwe, D. R. and Gupta, Bipin Kumar and Dhoble, S. J. and Deshmukh, Abhay D. (2019) Directly grown Sr-Co layered double hydroxide (LDH) entangled two dimensional nanosheet film with superior performances. Electrochimica Acta, 328. pp. 135063-135069. ISSN 0013-4686 |
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Relation |
http://npl.csircentral.net/4155/
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