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Ga induced 2D superstructural phase diagram on trenched Si(5512) surface

IR@NPL: CSIR-National Physical Laboratory, New Delhi

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Title Ga induced 2D superstructural phase diagram on trenched Si(5512) surface
 
Creator Kumar, Praveen
Kumar, Mahesh
Shivaprasad, S. M.
 
Subject Applied Physics/Condensed Matter
Physical Chemistry/Chemical Physics
 
Description The high index Si(5 5 12) surface offers morphological trenches, which can be interesting for epitaxial growth. In this study, the evolution of Ga adsorption at a very low flux rate of 0.03 ML/min on high index trenched Si(5 5 12) - 2 x 1 reconstructed surface at various substrate temperatures ranging from room temperature (RT) to 600 degrees C has been investigated using in-situ AES, LEED and EELS. The Auger uptake curves, which plot the Ga(LMM)/Si(LVV) Auger intensity ratio with Ga adsorption time, show that Ga grows in layer plus islands mode for substrate temperatures in the RT to 350 degrees C range, while it grows in Volmer-Weber (3D islands) for higher substrate temperatures (>350 degrees C). We also arrive at a complete 2D superstructural phase diagram for Ga/Si (5 5 12) interfacial system that shows the pathways to attain the different superstructural phases. The formation of Ga nanowires as (2 2 5),(3 3 7) phase and Ga 3D islands in the (1 1 2) - 6 x 1, (1 1 2) - 6 x 2 phases and other Ga induced superstructural phases like (7 7 17) + 2x(1 1 3), (2 2 5) + (3 3 7), 1 x 1 has been carefully followed. The electronic structures of each of the observed phases have been probed by EELS and each of them is shown to have characteristic features.
 
Publisher Elsevier
 
Date 2012-07
 
Type Article
PeerReviewed
 
Format application/pdf
 
Identifier http://npl.csircentral.net/3561/1/Ga%20induced%202D%20superstructural%20phase%20diagram.pdf
Kumar, Praveen and Kumar, Mahesh and Shivaprasad, S. M. (2012) Ga induced 2D superstructural phase diagram on trenched Si(5512) surface. Surface Science, 606 (13-14). pp. 1045-1049. ISSN 0039-6028
 
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