Processing of Waste Copper Converter Slag Using Organic Acids for Extraction of Copper, Nickel, and Cobalt
IR@NML: CSIR-National Metallurgical Laboratory, Jamshedpur
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Title |
Processing of Waste Copper Converter Slag Using
Organic Acids for Extraction of Copper, Nickel,
and Cobalt
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Creator |
Meshram, Pratima
Prakash, Uday Bhagat, Lalit Abhilash, Zhao, Hongbo van Hullebusch, Eric D |
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Subject |
Waste Utilization
Hydrometallurgy Minerals and Mining Waste Recycling Waste Management |
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Description |
An innovative, economical, and environmentally sound hydrometallurgical process has been proposed for recovering Cu, Ni, and Co from copper-rich converter slag by organic acids. In the leaching experiments, the eects of organic acid concentrations, pulp density,temperature, and time were investigated. Optimum recovery of 99.1% Cu, 89.2% Ni, 94% Co, and 99.2% Fe was achieved in 9–10 h at 308 K (35 oC) temperature and 15% pulp density with 2 N citric acid using <45 micron particles. Pourbaix diagrams of metal-water-citrate systems were supplemented to examine solubility of ligands at the desired conditions. Furthermore, the leaching mechanism was based on the SEM-EDS (energy-dispersive X-ray spectroscopy) and XRD characterization as well as the leaching results obtained.
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Publisher |
MDPI
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Date |
2020-03-23
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Type |
Article
PeerReviewed |
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Format |
application/pdf
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Identifier |
http://eprints.nmlindia.org/8136/2/minerals-10-00290-v2.pdf
Meshram, Pratima and Prakash, Uday and Bhagat, Lalit and Abhilash, and Zhao, Hongbo and van Hullebusch, Eric D (2020) Processing of Waste Copper Converter Slag Using Organic Acids for Extraction of Copper, Nickel, and Cobalt. Minerals, 10(3) (IF-2.380). p. 290. |
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Relation |
https://www.mdpi.com/2075-163X/10/3/290
http://eprints.nmlindia.org/8136/ |
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