Synthesis, Structural and Luminescent Properties of Novel Eu3+:Y2CaZnO5 Nanophosphor for White Light-Emitting Diodes
IR@NPL: CSIR-National Physical Laboratory, New Delhi
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| Title |
Synthesis, Structural and Luminescent Properties of Novel Eu3+:Y2CaZnO5 Nanophosphor for White Light-Emitting Diodes
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| Creator |
Rajeswari, R.
Jyothi, L. Jayasankar, C. K. Babu, S. Surendra Vijayan, N. Haranath, D. |
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| Subject |
Materials Science
Applied Physics/Condensed Matter Nanoscience/ Nanotechnology |
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| Description |
Novel red-emitting phosphors, Eu3+-doped Y2CaZnO5 (YCZ), were synthesized by modified urea assisted sol-gel combustion method. The X-ray diffraction analysis indicates the uniform formation of single-phase triclinic YCZ nanoparticles even when the concentration of Eu3+ ions is as high as 50 mol%. TEM measurements revealed that the particles have uniform size distributions in the range of 10-30 nm. Luminescence properties have been characterized using photoluminescence excitation, emission spectra and decay time measurements. A strong charge transfer band (CTB) at around 250 nm is observed which is due to the Eu-O interaction in the host along with the 4f-4f excitation bands due to Eu3+ ions in UV and blue regions. The excitation bands at 395 nm (F-7(0) -> L-5(6)) and 465 nm (F-7(0) -> D-5(2)) are found to be stronger than the CTB for Eu3+:YCZ nanophosphor, which match very well with the emission wavelength of commercial InGaN blue LED chip. Upon excitation to these wavelengths, a bright red emission from the D-5(0) level of Eu3+ ion is observed with CIE chromaticity coordinates (0.65, 0.34), which are found to be very close to the National Television System Committee (NTSC) for red phosphor (0.67, 0.33).
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| Publisher |
American Scientific Publishers
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| Date |
2013-11
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| Type |
Article
PeerReviewed |
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| Format |
application/pdf
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| Identifier |
http://npl.csircentral.net/3004/1/Synthesis%2C%20Structural.pdf
Rajeswari, R. and Jyothi, L. and Jayasankar, C. K. and Babu, S. Surendra and Vijayan, N. and Haranath, D. (2013) Synthesis, Structural and Luminescent Properties of Novel Eu3+:Y2CaZnO5 Nanophosphor for White Light-Emitting Diodes. Science of Advanced Materials, 5. pp. 1539-1545. ISSN 1947-2935 |
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| Relation |
http://npl.csircentral.net/3004/
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